ACS Catalysis, Год журнала: 2025, Номер unknown, С. 6226 - 6238
Опубликована: Апрель 2, 2025
Язык: Английский
ACS Catalysis, Год журнала: 2025, Номер unknown, С. 6226 - 6238
Опубликована: Апрель 2, 2025
Язык: Английский
Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 357, С. 124308 - 124308
Опубликована: Июнь 15, 2024
Язык: Английский
Процитировано
39ACS Energy Letters, Год журнала: 2024, Номер 9(4), С. 1743 - 1752
Опубликована: Март 26, 2024
Constructing vacancy-decorated heterojunction photocatalysts is a feasible strategy for highly efficient photooxidation of toluene to benzaldehyde. However, poor interface interaction and vacancy-triggered mismatched redox kinetics seriously impede photocatalytic activity improvement. Herein, chemically bonded Cs3Bi2Br9–x@AgBr core–shell with unified adsorption-redox sites fabricated via an in-situ light-assisted Ag+ insertion method. Experiments theoretical calculations demonstrate that the type-II band alignment interfacial Bi–Br–Ag bonds boosts charge separation. Moreover, because greater oxygen adsorption energy steric-hindrance effect AgBr shell, preferred site O2 modulated from Br vacancy (VBr, trapping holes) its corresponding reduction (AgBr, gathering electrons), thereby ensuring VBr-enhancing adsorption/oxidation on Cs3Bi2Br9. Therefore, exhibits improved benzaldehyde production rate 5.61 mmol g–1 h–1 (selectivity: 91%), outperforming pure Cs3Bi2Br9 by factor 6. This work underlines importance rational design heterointerface at atomic level in photocatalysis.
Язык: Английский
Процитировано
24Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 347, С. 123795 - 123795
Опубликована: Апрель 24, 2024
Язык: Английский
Процитировано
21Опубликована: Март 4, 2025
Язык: Английский
Процитировано
5Journal of Hazardous Materials, Год журнала: 2025, Номер unknown, С. 137423 - 137423
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
4Journal of Energy Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
3Environmental Science & Technology, Год журнала: 2024, Номер 58(11), С. 5153 - 5161
Опубликована: Март 8, 2024
Photothermal catalysis exhibits promising prospects to overcome the shortcomings of high-energy consumption traditional thermal and low efficiency photocatalysis. However, there is still a challenge develop catalysts with outstanding light absorption capability photothermal conversion for degradation atmospheric pollutants. Herein, we introduced Co3O4 layer Pt nanoclusters into three-dimensional (3D) porous membrane through atomic deposition (ALD) technique, leading Pt/Co3O4/AAO monolithic catalyst. The 3D ordered nanochannel structure can significantly enhance solar capacity light-trapping effect. Therefore, embedded Pt/Co3O4 catalyst be rapidly heated O2 adsorbed on clusters activated generate sufficient O2– species, exhibiting activity diverse VOCs (toluene, acetone, formaldehyde) degradation. Optical characterization simulation calculation confirmed that exhibited state-of-the-art notable localized surface plasmon resonance (LSPR) In situ diffuse reflectance infrared Fourier transform spectrometry (in DRIFTS) studies demonstrated irradiation accelerate intermediates during toluene acetone oxidation, thereby inhibiting byproduct accumulation. Our finding extends application AAO's optical properties in catalytic air
Язык: Английский
Процитировано
15Separation and Purification Technology, Год журнала: 2024, Номер 345, С. 127348 - 127348
Опубликована: Апрель 3, 2024
Язык: Английский
Процитировано
10Advanced Science, Год журнала: 2023, Номер 10(34)
Опубликована: Окт. 22, 2023
Solar-driven photothermal conversion of carbon dioxide (CO2 ) to methane (CH4 is a promising approach remedy energy shortage and climate changes, where highly efficient catalysts for CO2 methanation urgently need be designed. Herein, nickel-based (Ni/ZrO2 derived from metal-organic frameworks (MOFs) are fabricated studied methanation. The optimized catalyst 50Ni/ZrO2 achieves stable CH4 production rate 583.3 mmol g-1 h-1 in continuous stability test, which almost tenfold higher than that 50Ni/C-ZrO2 synthesized via commercial ZrO2 . Physicochemical properties indicate generates more tetragonal possesses oxygen vacancies (OVs) as well enhanced nickel-ZrO2 interaction. As result, exhibits the strong abilities light absorption light-to-heat conversion, superior adsorption capacities reactants (H2 , ), an intermediate product (CO), finally boosts formation. This work provides strategy design photothermocatalyst through utilizing MOFs-derived support.
Язык: Английский
Процитировано
22Chemical Engineering Journal, Год журнала: 2023, Номер 476, С. 146878 - 146878
Опубликована: Окт. 24, 2023
Язык: Английский
Процитировано
22