
Research Square (Research Square), Год журнала: 2024, Номер unknown
Опубликована: Дек. 4, 2024
Язык: Английский
Research Square (Research Square), Год журнала: 2024, Номер unknown
Опубликована: Дек. 4, 2024
Язык: Английский
Journal of Hazardous Materials, Год журнала: 2025, Номер 490, С. 137874 - 137874
Опубликована: Март 6, 2025
Язык: Английский
Процитировано
1Fuel, Год журнала: 2024, Номер 369, С. 131735 - 131735
Опубликована: Апрель 21, 2024
Язык: Английский
Процитировано
7ACS Earth and Space Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Фев. 12, 2025
Язык: Английский
Процитировано
1The Science of The Total Environment, Год журнала: 2024, Номер 919, С. 170633 - 170633
Опубликована: Фев. 9, 2024
Язык: Английский
Процитировано
6Environment & Health, Год журнала: 2024, Номер 2(7), С. 486 - 498
Опубликована: Апрель 2, 2024
Linalool, a high-reactivity volatile chemical product (VCP) commonly found in cleaning products and disinfectants, is increasingly recognized as an emerging contaminant, especially indoor air. Understanding the gas-phase oxidation mechanism of linalool crucial for assessing its impact on atmospheric chemistry human health. Using quantum calculations computational toxicology simulations, we investigated transformation toxicity evolution under low high NO/HO2· levels, representing outdoor environments. Our findings reveal that can undergo novel mechanisms involving concerted peroxy (RO2·) alkoxy radical (RO·) modulated autoxidation, particularly emphasizing importance cyclization reactions indoors. This expands widely known RO2·-dominated H-shift-driven autoxidation proposes generalized leads to formation low-volatility secondary organic aerosol (SOA) precursors. Toxicological analysis shows over half (TPs) exhibited higher carcinogenicity respiratory compared linalool. We also propose time-dependent toxic effects TPs assess their long-term toxicity. results indicate strong emission coupled with slow consumption rates lead significant health risks environment. The highlight complex air concerns regarding persistent during cleaning, which involves use or other VCPs.
Язык: Английский
Процитировано
4Environmental Science & Technology, Год журнала: 2024, Номер 58(27), С. 11935 - 11944
Опубликована: Июнь 24, 2024
Pollutants in human milk are critical for evaluating maternal internal exposure and infant external exposure. However, most studies have focused on a limited range of pollutants. Here, 15 pooled samples (prepared from 467 individual samples) three areas the Yangtze River Delta (YRD) China were analyzed by gas chromatography quadrupole time-of-flight mass spectrometry. In total, 171 compounds nine types preliminarily identified. Among these, 16 compounds, including 2,5-di-tert-butylhydroquinone 2-tert-butyl-1,4-benzoquinone, detected first time. Partial least-squares discriminant analysis identified ten area-specific pollutants, 2-naphthylamine, 9-fluorenone, 2-isopropylthianthrone, benzo[a]pyrene, among Shanghai (n = 3), Jiangsu Province 6), Zhejiang 6). Risk index (RI) values calculated indicated that legacy polycyclic aromatic hydrocarbons (PAHs) contributed only 20% total RIs PAHs derivatives, indicating more attention should be paid to with various functional groups. Nine priority pollutants YRD The important 4-tert-amylphenol, caffeine, 2,6-di-tert-butyl-p-benzoquinone, which associated apoptosis, oxidative stress, other health hazards. results improve our ability assess risks posed milk.
Язык: Английский
Процитировано
4Journal of Hazardous Materials, Год журнала: 2024, Номер 479, С. 135716 - 135716
Опубликована: Сен. 3, 2024
Язык: Английский
Процитировано
4Environmental Science & Technology, Год журнала: 2024, Номер unknown
Опубликована: Дек. 27, 2024
Black carbon or elemental (EC) in the atmosphere plays an ambiguous role acute respiratory toxic effects. Here, we evaluate contribution of EC to short-term toxicity (including cytotoxicity and oxidative stress potency) fine particulate matter (PM2.5) on human tract using vitro airway organoids cell lines. The potency per unit mass, including char soot, is more than 2 orders magnitude lower that polycyclic aromatic hydrocarbons (PAHs), which are coemitted from incomplete combustion. contributes approximately 1 order less PM2.5 PAHs, despite its positive associations with PM2.5-induced (p < 0.0001). Furthermore, PAHs contribute 71.9 ± 12.2% 61.9 32.8% overall emitted typical burning solid liquid fuels, respectively, while significantly correlates content (r = 0.94, p 0.002). Hence, not a cause inducing toxicity, likely attributed PAHs. These findings provide causal evidence for understanding health risks associated exposure further benefit establishing efficient air pollution control policies.
Язык: Английский
Процитировано
3Physics Letters B, Год журнала: 2025, Номер unknown, С. 139429 - 139429
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0ACS ES&T Air, Год журнала: 2025, Номер unknown
Опубликована: Март 30, 2025
Язык: Английский
Процитировано
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