Surface-Enhanced Raman Spectroscopy-Based Spatial Temperature Profiling in Space-Confined Hollow Carbon Nanospheres for a Reaction Mechanism Study DOI
Shiwei Li, Xiaoling Zhang,

C. Wang

и другие.

Analytical Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 25, 2025

Accurately sensing the spatial distribution of temperature, one most fundamental parameters, is crucial for understanding mechanism physicochemical process in confined space. However, traditional methods temperature measurement often show a very limited resolution and sensitivity. Herein, we develop surface-enhanced Raman spectroscopy (SERS) nanosensor to measure within hollow carbon nanospheres (HCNSs) study light-promoted Fenton-like catalyzed by Fe single-atom anchored on HCNSs. Based temperature-dependent SERS spectra phenyl isocyanide adsorbed Au nanoparticles, gradient nanocavity surface HCNSs, induced light-irradiation, sensed with sensitivity 0.8 °C. Furthermore, combining local reaction kinetics-temperature relationship, clarify that oxidation phenol peroxymonosulfate occurs at thus providing sound evidence homogeneous mechanism. Besides new strategy submicrometer resolution, this work also shows feasibility through locating reactive site.

Язык: Английский

Ultra-fast removal of aniline in the Fe(Ⅱ) activating peroxyacetic acid system via high-valent iron-oxo and hydroxy radical DOI
Caihong Zhang,

Zhenqi Xu,

Taizhuo Ma

и другие.

Journal of environmental chemical engineering, Год журнала: 2025, Номер unknown, С. 116061 - 116061

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Unraveling the Synergistic Cobalt-Nitrogen Cooperation in Biochar for Enhanced Peroxymonosulfate Activation: Mechanistic Insights into Nitrogen Configuration-Dependent Radical Pathways and Direct Electron Transfer DOI
Junhui Wang,

Caimei Lu,

K. Liu

и другие.

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
Unraveling the metal size-dependent origin in activating peracetic acid with cobalt single atoms: Collaboration of radical and non-radical mechanisms DOI
Chen Chen, Longlong Zhang,

Hongmin Li

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125252 - 125252

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Tuning the electronic structure of carbon fibers and Fenton-like oxidation pathways via in situ generation of MnO nanoparticles DOI

Rui Gan,

Lijuan Huang,

Wenxuan Shao

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125287 - 125287

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Surface-Enhanced Raman Spectroscopy-Based Spatial Temperature Profiling in Space-Confined Hollow Carbon Nanospheres for a Reaction Mechanism Study DOI
Shiwei Li, Xiaoling Zhang,

C. Wang

и другие.

Analytical Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 25, 2025

Accurately sensing the spatial distribution of temperature, one most fundamental parameters, is crucial for understanding mechanism physicochemical process in confined space. However, traditional methods temperature measurement often show a very limited resolution and sensitivity. Herein, we develop surface-enhanced Raman spectroscopy (SERS) nanosensor to measure within hollow carbon nanospheres (HCNSs) study light-promoted Fenton-like catalyzed by Fe single-atom anchored on HCNSs. Based temperature-dependent SERS spectra phenyl isocyanide adsorbed Au nanoparticles, gradient nanocavity surface HCNSs, induced light-irradiation, sensed with sensitivity 0.8 °C. Furthermore, combining local reaction kinetics-temperature relationship, clarify that oxidation phenol peroxymonosulfate occurs at thus providing sound evidence homogeneous mechanism. Besides new strategy submicrometer resolution, this work also shows feasibility through locating reactive site.

Язык: Английский

Процитировано

0