Chemical Society Reviews,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 4, 2024
This
review
explores
the
latest
developments
in
CO
2
electroreduction
based
systems,
including
coupling
reaction
co-reduction
cascade
and
integrated
capture
conversion
systems.
Environmental Science & Technology,
Год журнала:
2024,
Номер
58(25), С. 10881 - 10896
Опубликована: Июнь 11, 2024
One
of
the
most
promising
approaches
to
address
global
challenge
climate
change
is
electrochemical
carbon
capture
and
utilization.
Solid
electrolytes
can
play
a
crucial
role
in
establishing
chemical-free
pathway
for
CO2.
Furthermore,
they
be
applied
electrocatalytic
CO2
reduction
reactions
(CO2RR)
increase
utilization,
produce
high-purity
liquid
chemicals,
advance
hybrid
electro-biosystems.
This
review
article
begins
by
covering
fundamentals
processes
capture,
emphasizing
advantages
utilizing
solid
electrolytes.
Additionally,
it
highlights
recent
advancements
use
polymer
electrolyte
or
layer
CO2RR
with
multiple
functions.
The
also
explores
avenues
future
research
fully
harness
potential
electrolytes,
including
integration
performance
assessment
under
realistic
conditions.
Finally,
this
discusses
opportunities
challenges,
aiming
contribute
establishment
green
sustainable
society
through
valorization.
Chemical Science,
Год журнала:
2024,
Номер
15(37), С. 15087 - 15108
Опубликована: Янв. 1, 2024
This
review
emphasizes
the
fundamentals
of
CO
2
RR
in
neutral,
alkaline,
and
acidic
electrolytes
thoroughly
discusses
current
challenges
strategies
for
beyond
catalyst
itself.
Bioelectrochemistry,
Год журнала:
2025,
Номер
unknown, С. 109000 - 109000
Опубликована: Май 1, 2025
Methanol
assisted
microbial
electrosynthesis
(MES)
enables
butyrate
production
from
carbon
dioxide
and
methanol
using
external
electricity.
However,
the
effects
of
operational
parameters
on
formation
remain
unclear.
By
running
three
flat
plate
MES
reactors
with
fed-batch
mode
at
controlled
pH
values
(5.5,
6
7),
present
study
investigated
influence
by
comparing
process
performance,
community
structure,
genetic
potential.
The
highest
selectivity
(87
%
basis)
rate
0.3
g
L-1
d-1
were
obtained
6.
At
7,
a
comparable
was
achieved,
yet
lower
(70
%)
accompanied
acetate
production.
Butyrate
considerably
hindered
5.5,
reaching
0.1
d-1,
while
reached
up
to
81
%.
CO2
consumption
increased
pH,
along
more
negative
cathodic
potential
redox
Furthermore,
affected
thermodynamical
feasibility
involved
reactions.
results
metagenomic
analyses
suggest
that
Eubacterium
callanderi
dominated
communities
all
values,
which
responsible
for
assimilation
via
Wood-Ljungdahl
pathway
likely
main
producer
reverse
β-oxidation
pathway.