Oxidation of Polycyclic Aromatic Hydrocarbons (PAHs) Triggered by a Photochemical Synergistic Effect between High- and Low-Molecular-Weight PAHs DOI
Jiachun Li, Yifan Zhu,

Xiaojie Ji

и другие.

Environmental Science & Technology, Год журнала: 2024, Номер unknown

Опубликована: Сен. 30, 2024

Photooxidation of polycyclic aromatic hydrocarbons (PAHs), which are widely observed in atmospheric particulate matter (PM), largely determines their fate. In the environment, PAHs highly complex chemical composition, and a great variety tend to co-occur. Despite extensive investigation on photochemical behavior individual PAH molecules, interaction among these coexisting is still not well understood. Here, we show that during photooxidation, there strong synergistic effect extracted from soot particles. We find neither small with low molecular weights 200-350 Da 4-8 rings (named

Язык: Английский

Absence of a Causal Link between Elemental Carbon Exposure and Short-Term Respiratory Toxicity in Human-Derived Organoids and Cellular Models DOI
Chen Xiu, Di Wu, Yifei Tan

и другие.

Environmental Science & Technology, Год журнала: 2024, Номер unknown

Опубликована: Дек. 27, 2024

Black carbon or elemental (EC) in the atmosphere plays an ambiguous role acute respiratory toxic effects. Here, we evaluate contribution of EC to short-term toxicity (including cytotoxicity and oxidative stress potency) fine particulate matter (PM2.5) on human tract using vitro airway organoids cell lines. The potency per unit mass, including char soot, is more than 2 orders magnitude lower that polycyclic aromatic hydrocarbons (PAHs), which are coemitted from incomplete combustion. contributes approximately 1 order less PM2.5 PAHs, despite its positive associations with PM2.5-induced (p < 0.0001). Furthermore, PAHs contribute 71.9 ± 12.2% 61.9 32.8% overall emitted typical burning solid liquid fuels, respectively, while significantly correlates content (r = 0.94, p 0.002). Hence, not a cause inducing toxicity, likely attributed PAHs. These findings provide causal evidence for understanding health risks associated exposure further benefit establishing efficient air pollution control policies.

Язык: Английский

Процитировано

3

Variations in polycyclic aromatic hydrocarbons concentrations and their contribution to aerosol optical depth during the COVID-19 outbreak: A study in Yokohama using generalized additive model DOI Creative Commons
Weidong Jing,

Kohei Nakano,

Ryosuke Mitani

и другие.

Atmospheric Pollution Research, Год журнала: 2025, Номер 16(8), С. 102547 - 102547

Опубликована: Апрель 16, 2025

Язык: Английский

Процитировано

0

A solid-state infrared laser for two-step desorption–ionization processes in single-particle mass spectrometry DOI Creative Commons

Marco Schmidt,

Haseeb Hakkim,

Lukas Anders

и другие.

Atmospheric measurement techniques, Год журнала: 2025, Номер 18(11), С. 2425 - 2437

Опубликована: Июнь 5, 2025

Abstract. Recent advancements in single-particle mass spectrometry (SPMS) have enabled the detection of aromatic hydrocarbons at individual particle level conjunction with inorganic/refractory components. However, laser desorption (LD) organic material from particles prior to their ionization a two-step process necessitates pulsed infrared lasers adequate pulse energy that can be irregularly triggered on detected particles. Pulsed CO2 10.6 µm wavelength been traditionally utilized, yet these are bulky and costly require regular maintenance, including gas exchange or continuous supply. In this study, we present application prototype solid-state based an erbium-doped yttrium aluminum garnet (Er:YAG) crystal, emitting long pulses 200 µs 3 as compact, cost-effective, user-friendly alternative for LD. We directly compared new commonly used found similar performance LD both laboratory ambient air experiments. With exception slightly increased fragmentation observed due its beam profile, no qualitative differences were noted resulting spectra. Additionally, novel (LD-REMPI–LDI) conventional single-step LDI regarding potential detect polycyclic (PAHs) inorganics field The combined methods demonstrated superior PAHs, Er:YAG laser. addition higher sensitivity lower PAHs when LDI, it is less dependent matrix, sharing benefits traditional but extending capability combine PAH measurements LDI-based inorganic compounds.

Язык: Английский

Процитировано

0

Oxidation of Polycyclic Aromatic Hydrocarbons (PAHs) Triggered by a Photochemical Synergistic Effect between High- and Low-Molecular-Weight PAHs DOI
Jiachun Li, Yifan Zhu,

Xiaojie Ji

и другие.

Environmental Science & Technology, Год журнала: 2024, Номер unknown

Опубликована: Сен. 30, 2024

Photooxidation of polycyclic aromatic hydrocarbons (PAHs), which are widely observed in atmospheric particulate matter (PM), largely determines their fate. In the environment, PAHs highly complex chemical composition, and a great variety tend to co-occur. Despite extensive investigation on photochemical behavior individual PAH molecules, interaction among these coexisting is still not well understood. Here, we show that during photooxidation, there strong synergistic effect extracted from soot particles. We find neither small with low molecular weights 200-350 Da 4-8 rings (named

Язык: Английский

Процитировано

2