Unveiling the Critical Role of Spatial Organization on Enzymatic Cascade Reactions in a Crystalline Framework with Hierarchical Porosity DOI
Fanrui Sha,

Geun‐Ho Han,

K. Liu

и другие.

ACS Materials Letters, Год журнала: 2024, Номер unknown, С. 409 - 416

Опубликована: Дек. 30, 2024

Enzymatic cascades are critical for energy conversion and chemical transformations in living organisms. Their ecofriendly nature high selectivity catalysis make them promising candidates improving cell-free systems. However, their applications have been limited by poor stability. Immobilized cascades, which can enhance activity, remain underexplored due to challenges such as ambiguous support structures difficulties controlling enzyme distribution. In this work, we employed NU-1510, a novel metal–organic framework (MOF) with crystalline hierarchical pore structure, stabilize an cascade that oxidizes ethanol acetaldehyde subsequently acetic acid. The impact of spatial organization on the kinetics was further investigated thanks structure MOF host. These findings pave way design advanced biocatalytic systems improved efficiency durability, potentially transforming sustainable manufacturing conversion.

Язык: Английский

Heterogeneous catalysis for the environment DOI
Jun Liu,

Rihana Burciaga,

S. Q. Tang

и другие.

The Innovation Materials, Год журнала: 2024, Номер unknown, С. 100090 - 100090

Опубликована: Янв. 1, 2024

<p>Anthropogenic climate and environmental changes increasingly threaten the sustainability of life on Earth, hindering sustainable development human societies. These detrimental ecological are driven by activities that have elevated atmospheric levels greenhouse gases toxic substances, increased inorganic organic pollutants in water bodies, led to accumulation solid waste soils. Over next two three decades, impacts change, pollution, soil contamination expected intensify, posing increasing risks health global stability. Considering these trends, it is essential implement robust mitigation adaptation strategies. This paper analyzes pollution problems from perspectives atmospheric, water, contamination. It summarizes current research heterogeneous catalysis for treating gaseous, liquid, phases, with an emphasis key challenges applying catalytic conversion technologies cost-effective industrial settings. Finally, strategies mitigating via discussed material flow, energy data flow. aims offer scientific insights enhance future practice remediation.</p>

Язык: Английский

Процитировано

5

Innovations in packed-bed reactors utilizing immobilized lipase catalysts: A comprehensive technical and scientific review DOI
Allison Silva, Luciana Rocha Barros Gonçalves, Ivanildo José da Silva

и другие.

Molecular Catalysis, Год журнала: 2025, Номер 573, С. 114814 - 114814

Опубликована: Янв. 5, 2025

Язык: Английский

Процитировано

0

Single-atom nanozymes for enhanced electrochemical biosensing: A review DOI

Xiaofei Zhu,

Can Xiong, Huang Zhou

и другие.

Talanta, Год журнала: 2025, Номер 294, С. 128179 - 128179

Опубликована: Апрель 25, 2025

Язык: Английский

Процитировано

0

Effects of the Hot-Drawing Process on the Pore Parameters, Gas Absorption and Mechanical Performances of Activated Carbon-Loaded Porous Poly(m-Phenylene Isophthalamide) Composite Fibres DOI Open Access
Xiaosong Li, Bo Li, Qibin Xu

и другие.

Polymers, Год журнала: 2024, Номер 16(24), С. 3452 - 3452

Опубликована: Дек. 10, 2024

Poor breathability, inadequate flexibility, bulky wearability, and insufficient gas-adsorption capacity always limit the developments applications of conventional chemical protective clothing (CPC). To create a lightweight, breathable, flexible fabric with high gas-absorption capacity, activated carbon (AC)-loaded poly(m-phenylene isophthalamide) (PMIA) porous composite fibres were fabricated from mixed wet-spinning process integrated solvent-free phase separation process. By manipulating pore parameters as-spun fibres, exposure-immobilization AC particles on fibre surface can offer higher better AC-loading stability. improve mechanical properties AC-loaded further optimize pore-locking structures, impact hot-drawing evolution corresponding (including gas absorption performance, stability during loading) was clarified. After process, inhomogeneous morphologies composed mesopores/micropores changed into homogeneous decreased mesopores. With decrease in structural defects morphologies, tensile strength PMIA porous-drawn increased to 1.5 cN/dtex. Meanwhile, greater total volume specific area after hot drawing also maintained drawn at 98.53 mg/g. Furthermore, showed comparable performance commercial FFF02 layer terms static behaviour for different molecules absorption–desorption multi-cycling evaluations. In addition, due size reduction mesopores loading stretched more substantial.

Язык: Английский

Процитировано

0

Synthesis, characterization, selective degradation of organic dyes and mechanism study of two novel Mn(II)-based coordination polymers DOI
Chang Sun, Juan Jian,

Na Lv

и другие.

Journal of Molecular Structure, Год журнала: 2024, Номер 1327, С. 141114 - 141114

Опубликована: Дек. 26, 2024

Язык: Английский

Процитировано

0

Unveiling the Critical Role of Spatial Organization on Enzymatic Cascade Reactions in a Crystalline Framework with Hierarchical Porosity DOI
Fanrui Sha,

Geun‐Ho Han,

K. Liu

и другие.

ACS Materials Letters, Год журнала: 2024, Номер unknown, С. 409 - 416

Опубликована: Дек. 30, 2024

Enzymatic cascades are critical for energy conversion and chemical transformations in living organisms. Their ecofriendly nature high selectivity catalysis make them promising candidates improving cell-free systems. However, their applications have been limited by poor stability. Immobilized cascades, which can enhance activity, remain underexplored due to challenges such as ambiguous support structures difficulties controlling enzyme distribution. In this work, we employed NU-1510, a novel metal–organic framework (MOF) with crystalline hierarchical pore structure, stabilize an cascade that oxidizes ethanol acetaldehyde subsequently acetic acid. The impact of spatial organization on the kinetics was further investigated thanks structure MOF host. These findings pave way design advanced biocatalytic systems improved efficiency durability, potentially transforming sustainable manufacturing conversion.

Язык: Английский

Процитировано

0