Multiscopic Microenvironment Engineering in Nitrate Electrocatalytic Reduction DOI
Lin Gu,

Yuting Cong,

Ziyang Wu

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 15, 2025

Abstract The electrocatalytic reduction of nitrate (NO 3 RR) is essential for environmental remediation and the nitrogen cycle, yet effects local microenvironment at multiple‐level on catalysis remain largely unclear. This review focuses analyzing impact microenvironmental engineering NO RR from multiscopic. Four aspects are detailed understanding regulation in RR, that are, electronic/molecular interactions (theory simulations), catalysts/reactants (intrinsic activity modulation), solution (anion/cation effect) diffusion (electrocatalytic reactor design). Additionally, relevant situ characterization techniques various material systems (metals, compounds, carbon composites, organic composites) discussed detail can modulate reaction microenvironment. Given potential large‐scale applications, necessary designs also summarized industrial level optimized performance. concludes by outlining future research directions enhancing microenvironment, which will be crucial developing efficient catalysts expanding application microenvironments.

Язык: Английский

Intercropping Different Legumes in Tea Plantation Improves Soil Properties and Tea Quality Components by Regulating Rhizosphere Soil Microorganisms DOI Creative Commons

M. Chen,

Pinqian Zhou,

Qiang Bao

и другие.

Agronomy, Год журнала: 2025, Номер 15(3), С. 511 - 511

Опубликована: Фев. 20, 2025

Intercropping legumes is an effective and sustainable planting pattern that has the benefit of decreasing chemical fertilizer input improving soil environment. However, effects reduction intercropping different on nutrients, microorganisms, tea quality remain elusive. Hereby, compared with 100% (CK), Sesbania cannabina (SC) Crotalaria pallida Blanco (CP) were selected as intercropped plant 70% to investigate its effect quality. The results showed monocropping, had greater concentrations labile organic matter, nitrate nitrogen, ammonia inorganic alkali-hydrolyzable nitrogen. systems significantly enhanced content non-ester-type catechins (catechin gallocatechin) ester-type (epicatechin gallate). In SC, gallocatechin, catechin, epicatechin gallate increased by 146.67%, 107.69%, 21.05%, respectively, while in CP, these three compounds 166.67%, 84.62%, 19.08%, respectively. Significant differences microbial composition also observed under systems. Actinobacteria, Rhodoplanes, Thaumarchaeota obviously Rhodanobacter, Pseudolabrys, Pedosphaera manifestly improved CP those monoculture. Moreover, abundances CNP cycling functional genes, such gpmB, mch, accD6, pgi-pmi, mcr, glmS, ACOX1 fadB (carbohydrate metabolism), nirD narI (nitrification), pmoB-amoB hao (dissimilatory N reduction), phoN (organic phosphoester hydrolysis). relationship between qualities was mainly established nutrition abundance C microorganisms. This study provides more information genes tea/legume plantations offers a basis for higher-performance pattern.

Язык: Английский

Процитировано

1

Bioremediation Potential of Sulfadiazine-Degrading Bacteria: Impacts on Ryegrass Growth and Soil Functionality DOI
Minghao Yin, Ping Li,

Chengzhuang Chen

и другие.

Journal of Hazardous Materials, Год журнала: 2025, Номер unknown, С. 138012 - 138012

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Iron, Sulfur, and Carbon Dynamics Collectively Regulate the Fate of Cadmium over the Sulfidation-Reoxidation Cycle DOI
Qian Sun, Edward D. Burton, Zhenghong Yu

и другие.

Environmental Science & Technology, Год журнала: 2025, Номер unknown

Опубликована: Апрель 6, 2025

Cadmium bioavailability is sensitive to redox fluctuations, with its fate linked the coupled dynamics of Fe, S, and C. This study examines behavior Cd-loaded ferrihydrite (Fh) with/without organic matter (OM) undergoing S(-II)-induced reduction followed by O2-induced reoxidation. During sulfidation, S(-II) was fully consumed, Fh partially reduced Fe(II) species, some OM released from surface. Meanwhile, Cd initially adsorbed on completely converted CdS, regardless loading or presence OM. Upon reoxidation, species were reoxidized Fe(III) oxides, which recaptured OM, while solid-phase oxidized S0 sulfate. Concurrently, partial oxidation CdS occurred, mainly driven H2O2 generated during oxidation, minor contributions •OH O2, but inhibited primarily scavenging H2O2. Released predominantly readsorbed oxides. Additionally, structurally incorporated into newly formed oxides encapsulated within oxide aggregates. However, interactions formation these species. These findings provide insights molecular-scale mechanisms governing in redox-dynamic environments.

Язык: Английский

Процитировано

0

Lignosulfonate Improves Soil Fertility by Promoting Exchangeable Al3+ Immobilization and Facilitating Its Interaction with Soil Enzymes through Active Functional Group Surfaces DOI
Debo He, Bo Zhu

Journal of Agricultural and Food Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 23, 2025

Soil acidification threatens soil health and sustainable agriculture, conventional mitigation strategies have various limitations, underscoring the need for creation of more effective alternatives. In this study, we evaluated effects calcium lignosulfonate (CL) on physicochemical properties acidic soils (Rs, K2j, J2s) through pot experiments. Additionally, molecular modeling calculations were employed to investigate interaction mechanisms between CL exchangeable acidity active enzyme. The results showed that was superior lime in reducing phytotoxic Al3+, enhancing buffering capacity, improving fertility plant biomass accumulation. These benefits attributed strong competitive adsorption Al3+ by surface functional groups, enhanced interactions enzymes, restructuring microbial communities. findings provide valuable insights developing efficient amendments mitigate acidification, ultimately agricultural productivity.

Язык: Английский

Процитировано

0

Nitrogen deposition reshapes biological nitrogen fixation and soil diazotrophic communities across urban and rural forests DOI
Ruoxian Fu,

Dianlong Ge,

Jinsheng Li

и другие.

CATENA, Год журнала: 2025, Номер 256, С. 109101 - 109101

Опубликована: Май 3, 2025

Язык: Английский

Процитировано

0

Integrating Agronomic and Molecular Advancements to Enhance Nitrogen Use Efficiency (NUE) and Promote Sustainable Rice Production DOI Creative Commons
Uttam Bahadur Kunwar, Nazer Manzoor,

Jiancheng Wen

и другие.

Nitrogen, Год журнала: 2025, Номер 6(2), С. 34 - 34

Опубликована: Май 14, 2025

Rice is a major crop for half of the world’s population, and nitrogen (N) fertilizers play crucial role in its production. However, imbalanced N fertilizer uses traditional fertilization practices have led to low use efficiency (NUE), increased footprints, reduced rice yields farmers’ income. There are limited studies where integration both agronomic molecular advancements enhance NUE discussed, particularly developing countries. This review highlights novel strategies NUE, yields, profitability, while minimizing environmental impact. The include 4R Nutrient Stewardship framework, enhanced (EENFs), nano-fertilizers, biochar-based fertilizers, biological fixation, sensor-based management rice-growing mechanisms focus on uptake, assimilation, utilization, highlighting hormones, key genes, transcription factors (TFs), regulatory pathways. Moreover, we examine promising genotypes cultivars with improved grain yield. Additionally, this paper offers deep insights into recent genetics, such as multi-omics approaches (transcriptomics, metabolomics, metagenomics), Genome-Wide Association Study (GWAS), Quantitative Traits Loci mapping (QTLs), Single Nucleotide Polymorphisms (SNPs) analysis, Clustered Regularly Interspaced Short Palindromic Repeats (CRISPR-Cas9)-mediated genome editing, which serve valuable tools

Язык: Английский

Процитировано

0

Multiscopic Microenvironment Engineering in Nitrate Electrocatalytic Reduction DOI
Lin Gu,

Yuting Cong,

Ziyang Wu

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 15, 2025

Abstract The electrocatalytic reduction of nitrate (NO 3 RR) is essential for environmental remediation and the nitrogen cycle, yet effects local microenvironment at multiple‐level on catalysis remain largely unclear. This review focuses analyzing impact microenvironmental engineering NO RR from multiscopic. Four aspects are detailed understanding regulation in RR, that are, electronic/molecular interactions (theory simulations), catalysts/reactants (intrinsic activity modulation), solution (anion/cation effect) diffusion (electrocatalytic reactor design). Additionally, relevant situ characterization techniques various material systems (metals, compounds, carbon composites, organic composites) discussed detail can modulate reaction microenvironment. Given potential large‐scale applications, necessary designs also summarized industrial level optimized performance. concludes by outlining future research directions enhancing microenvironment, which will be crucial developing efficient catalysts expanding application microenvironments.

Язык: Английский

Процитировано

0