FirePhysChem,
Год журнала:
2023,
Номер
4(3), С. 201 - 210
Опубликована: Ноя. 23, 2023
In
the
field
of
energetic
materials,
traditional
materials
with
high
toxicity
or
other
disadvantages
are
mostly
used.
There
is
an
urgent
need
for
trinitrotoluene
replacements
(TNT),
which
itself
toxic
and
its
production
problematic
due
to
red
wastewater.
New
should
be
safe
handle,
have
good
performance,
inexpensive
synthesize.
Nitratoalkylazoles
known
low
melting
points
properties
compared
TNT.
this
paper,
seven
compounds
synthesized
starting
from
5-methyltetrazole,
5-hydroxymethyltetrazole
4,5-bishydroxymethyltriazole.
The
nitrates
characterized
in
terms
their
physical,
chemical,
properties.
Of
those
compounds,
five
solid,
between
27
110°C,
two
liquid.
Methylation
hydroxyalkylation
were
performed
discussed
extensively.
organic
nitrate
introduced
last
step
so
that
synthesis
remains
scalable.
Correlations
molecular
geometry
explained.
Calculations
indicate
detonation
velocities
6-11%
higher
than
A
discussion
effect
isomerism
on
leads
surprising
insights
help
focus
accelerate
research
replacement
Journal of Heterocyclic Chemistry,
Год журнала:
2022,
Номер
60(4), С. 537 - 565
Опубликована: Окт. 13, 2022
Abstract
Among
different
heterocyclic
compounds,
isoxazole
and
their
analogues
are
very
important
classes
of
compounds
as
they
display
an
extensive
range
biological
actions.
This
makes
such
scaffolds
structures
in
the
field
medicinal
chemistry.
From
literature
assessment,
is
clinically
proven
to
be
effective
anti‐bacterial,
anti‐fungal,
anti‐inflammatory,
anti‐cancer,
anti‐tubercular,
anti‐neoplastic
agent.
The
derivatives
which
exhibits
adjustment
structure
have
shown
a
high
degree
variety
properties
evident
them
beneficial
progress
novel
bioactive
drugs
show
enhanced
effectiveness
along
with
minor
harmfulness.
Structural
aspects
having
aromaticity
weaker
nitrogen‐oxygen
bonding
provide
potential
site
for
ring
cleavage.
Thus,
this
system
allows
easier
modifications
substituents
consequently
make
useful
intermediates
various
synthetic
routes
compounds.
Hence,
synthesis
evaluation
isoxazole‐containing
molecules
wider
therapeutic
consequences
always
topic
interest
chemists.
light
comprehensive
research
on
isoxazole,
it
thought
worthwhile
review
pathways
broad
spectrum
Russian Chemical Reviews,
Год журнала:
2024,
Номер
93(2), С. RCR5109 - RCR5109
Опубликована: Янв. 16, 2024
The
study
of
high-energy
materials
based
on
poly
nitrogen-
and
nitrogen-oxygen-containing
heterocycles
is
one
the
most
important
relevant
modern
interdisciplinary
research
areas
at
intersection
organic
physical
chemistry
science.
Among
such
heterocycles,
1,2,4-oxadiazole
ring
a
rather
interesting
building
block
for
synthesis
new
energetic
compounds.
Although
1,2,4-oxadiazoles
has
been
developed
more
than
100
years,
these
have
only
recently
become
known
are
currently
"hot
spots"
in
this
field
This
review
systematizes
published
methods
features
reactivity
1,2,4-oxadiazole-based
Mono-
bis(1,2,4-oxadiazoles)
as
well
structures
containing
other
azoles
pyrazole,
1,2,5-oxadiazole,
1,3,4-oxadiazole,
1,2,3-triazole,
1,2,4-triazole
tetrazole
considered.
For
series
structurally
similar
compounds,
their
physicochemical
properties
summarized
factors
affecting
particular
parameter
discussed.<br>
Bibliography
—
123
references.
Dalton Transactions,
Год журнала:
2023,
Номер
52(11), С. 3449 - 3457
Опубликована: Янв. 1, 2023
A
facile
synthesis
of
phenylene-bridged
insensitive
energetic
materials
was
developed.
Most
title
compounds
are
suitable
propellants
for
rocket
propulsion
and
ethanol-based
fuel
blends.
Three
potential
melt-castable
materials.
ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 22, 2025
The
design
of
high-energy-density
materials
(HEDMs)
and
the
investigation
energy
limits
have
consistently
represented
a
focal
point
significant
challenge
in
research.
This
study
prepared
hydrogen-free
compound,
BLG-102,
with
high
nitrogen
content
(66.6%)
using
an
energetic
block
based
on
long
chain
(N6).
BLG-102
has
crystal
density
1.85
g·cm-3,
measured
1.82
g·cm-3.
It
also
achieves
zero
oxygen
balance
(based
CO),
excellent
enthalpy
formation,
good
conjugate
planarity
aromaticity.
demonstrates
exceptional
detonation
performance
velocity
(VD
=
9311
m·s-1)
pressure
(P
38.5
GPa).
These
values
are
superior
to
well-known
compound
RDX
8991
m·s-1,
P
35.2
GPa),
comparable
HMX
9144
39.2
Nevertheless,
exhibits
slightly
higher
but
acceptable
sensitivity
(IS
5
J,
FS
54
N).
remarkable
capabilities
laser
initiation.
Notably,
10
mg
charge
can
effectively
detonate
20
RDX,
producing
pore
diameter
11.44
mm
lead
plate
(2
thick).
integrated
approach
concept─combining
nitro,
azide,
structures
1,2,4-triazole
framework─significantly
enhances
compounds.
breaks
through
limit
already
known
1,2,4-triazole-based
compounds
provides
new
idea
for
synthesis
HEDMs
performance.
The Journal of Chemical Physics,
Год журнала:
2025,
Номер
162(19)
Опубликована: Май 16, 2025
The
thermal
decomposition
of
azidoethyl
methyl
sulfide
was
studied
by
real-time
UV-photoelectron
spectroscopy
(UV-PES)
at
temperatures
ranging
from
773
to
1023
K.
Different
ionization
energies
were
obtained
using
density
functional
theory
calculations
assign
UV-PES
spectra.
complete
active
space
self-consistent
field
and
multistate
second-order
perturbation
methods
used
predict
the
formation
different
species
present
in
process.
N2
S-methyl-N-sulfenylethanimine
are
generated
first
step
reaction
is
dissociation
molecule
into
nitrene
nitrogen.
spin
state
(singlet
or
triplet)
formed
temperature-dependent.
At
low
(T
≤
650
K),
both
states
with
almost
same
probability;
contrast,
high
≥
1000
singlet
majority
intermediate.
From
this
nitrene,
three
stable
products
detected
experiments:
an
imine
derivative,
a
four-member
cyclic
sulfenyl
derivative.
Dalton Transactions,
Год журнала:
2021,
Номер
50(39), С. 13656 - 13660
Опубликована: Янв. 1, 2021
Hydroxymethylation
of
5,5′-bistetrazole
paves
the
way
for
2,2′
di(azidomethyl)-5,5′-bistetrazole
–
highlight
this
work.
It's
initiation
capability
and
thermal
behavior
offers
application
as
melt-castable
metal-free
green
primary
explosive.
