Organic Letters, Год журнала: 2025, Номер unknown
Опубликована: Май 2, 2025
Herein, we report a Pd-catalyzed β-C(sp3)-H biarylation of native amides using diaryliodonium salts. A pyridine-3-sulfonic acid ligand that might stabilize the substrate-bound palladium species was found to be essential for high catalytic activity. The reaction displayed broad scope and showed excellent compatibility with diverse cyclic salts amide substrates. retained iodo functionality on product provides versatile handle further increasing molecular complexity.
Язык: Английский
Процитировано
0Transition Metal‐Catalyzed C−H Activation/Functionalization of 8‐Methylquinolines
The Chemical Record, Год журнала: 2024, Номер 24(11)
Опубликована: Окт. 18, 2024
Abstract 8‐Methylquinoline is regarded as an ideal substrate to participate in diversely C(sp 3 )−H functionalization reactions. The presence of the chelating nitrogen atom enables 8‐methylquinoline easily form cyclometallated complexes with various transition metals, leading selective synthesis functionalized quinolines. Considering great importance quinoline cores medicinal chemistry, this review article, we have covered publications related C−H activation and under metal catalysis during last decade.
Язык: Английский
Процитировано
1Six-membered ring systems: pyridines and benzo derivatives
Progress in heterocyclic chemistry, Год журнала: 2023, Номер unknown, С. 383 - 425
Опубликована: Янв. 1, 2023
Язык: Английский
Процитировано
1Suzuki-Miyaura/Mizoroki-Heck Coupling Cascade to Access 2,2'-Bifunctionalized Biaryls
Chemical Communications, Год журнала: 2024, Номер unknown
Опубликована: Дек. 23, 2024
A cascade bifunctionalization strategy successfully delivering otherwise difficult to achieve 2,2′-bifunctionalized biaryls via Suzuki–Miyaura couling and Mizoroki–Heck reaction on cyclic diarylidonium salts is presented.
Язык: Английский
Процитировано
0Diaryliodonium Salts
ACS in focus, Год журнала: 2024, Номер unknown
Опубликована: Июнь 17, 2024
Процитировано
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