Visible-Light-Induced Difunctionalization of 3-Butenoic Acid with Bromodifluoromethyl Heteroarylsulfones DOI
Qianqian Liu, Xiaoping Wang,

Xuefeng Gu

и другие.

Organic Letters, Год журнала: 2024, Номер 26(30), С. 6449 - 6453

Опубликована: Июль 22, 2024

Herein, we report a visible-light-induced iridium-promoted direct bifunctionalization of 3-butenoic acid with bromodifluoromethyl heteroarylsulfones. This methodology enables the concurrent introduction difluoromethyl heteroarylsulfone and bromine groups into under mild reaction conditions. Various

Язык: Английский

Three-component dicarbofunctionalization of allylamines via nucleopalladation pathway: unlocking vicinal and geminal selectivity DOI Creative Commons

Nityananda Ballav,

Shib Nath Saha,

Shailesh Yadav

и другие.

Chemical Science, Год журнала: 2024, Номер 15(13), С. 4890 - 4896

Опубликована: Янв. 1, 2024

A palladium( ii )-catalyzed vicinal and geminal selective dicarbofunctionalization of allylamine embedded in a removable picolinamide auxiliary is developed by exploiting nucleopalladation-triggered intermolecular three-component coupling reaction.

Язык: Английский

Процитировано

6
Regioselective intermolecular carboamination of allylamines via nucleopalladation: empowering three-component synthesis of vicinal diamines DOI Creative Commons
Shib Nath Saha,

Nityananda Ballav,

Suman Ghosh

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Intermolecular carboamination of allyl amines under Pd( ii )-catalysis is reported, expediting the synthesis vicinal diamines embedded in a functionally enriched linear carbon framework with high yields and exclusive Markovnikov selectivity.

Язык: Английский

Процитировано

5
Pd-Catalyzed Three-Component 1,1-Carboamination of 4-Pentenoic Acid DOI

Lihua Mao,

Xiangwen Tan,

Jiahao Wu

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 13, 2025

Herein, we describe a method to achieve the three-component 1,1-carboamination of 4-pentenoic acid by palladium catalysis, successfully constructing δ-lactam derivatives. The protocol features excellent 1,1-regioselectivity, high step and atom economy, good functional group tolerance.

Язык: Английский

Процитировано

0
Pd-catalyzed Markovnikov selective oxidative amination of 4-pentenoic acid DOI

Lihua Mao,

Chao Liu,

Xiangwen Tan

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(71), С. 9626 - 9629

Опубликована: Янв. 1, 2024

A palladium-catalyzed and ligand-controlled strategy for the Markovnikov selective oxidative amination of 4-pentenoic acid has been described.

Язык: Английский

Процитировано

2
Palladium Catalysis: Dependence of the Efficiency of C–N Bond Formation on Carboxylate Ligand and Metal Carboxylate or Carboxylic Acid Additive DOI Creative Commons
Jacques Мuzart

ACS Omega, Год журнала: 2024, Номер unknown

Опубликована: Март 8, 2024

The Pd-catalyzed inter- and intramolecular reactions of nitrogen compounds are often carried out with palladium carboxylates, sometimes in the presence carboxylic acids or alkali metal carboxylates. This Mini-Review highlights dependence reaction efficiency on nature ligand carboxylate additives. proposed mechanisms presented with, as far possible, personal comments.

Язык: Английский

Процитировано

0
Visible-Light-Induced Difunctionalization of 3-Butenoic Acid with Bromodifluoromethyl Heteroarylsulfones DOI
Qianqian Liu, Xiaoping Wang,

Xuefeng Gu

и другие.

Organic Letters, Год журнала: 2024, Номер 26(30), С. 6449 - 6453

Опубликована: Июль 22, 2024

Herein, we report a visible-light-induced iridium-promoted direct bifunctionalization of 3-butenoic acid with bromodifluoromethyl heteroarylsulfones. This methodology enables the concurrent introduction difluoromethyl heteroarylsulfone and bromine groups into under mild reaction conditions. Various

Язык: Английский

Процитировано

0