Auto-Tandem Catalyst: From Allylic Alcohols to Secondary Alcohols via Redox Isomerization/Atmospheric Hydrogenation in Water Catalyzed by a Water-Soluble Iridium Complex Bearing a Functional Ligand
Inorganic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 13, 2025
A
water-soluble
iridium
complex
[Cp*Ir(6,6′-(OH)2-2,2′-bpy)(H2O)][OTf]2
was
found
to
be
an
efficient
autotandem
catalyst
for
the
synthesis
of
secondary
alcohols
via
redox
isomerization/atmospheric
hydrogenation
in
water.
The
OH
groups
bpy
ligand
are
a
key
factor
activity
catalyst.
Then,
mechanistic
experiments
and
practical
utilization
catalytic
system
were
presented.
Язык: Английский
Poly(2,2′-Bibenzimidazole)–Supported Iridium Complex: A Recyclable Metal–Polymer Ligand Bifunctional Catalyst for the N-Methylation of Amines with Methanol
Inorganic Chemistry,
Год журнала:
2024,
Номер
63(32), С. 15072 - 15080
Опубликована: Июль 27, 2024
The
design
and
development
of
new
types
catalysts
is
one
the
most
important
topics
for
modern
chemistry.
Herein,
a
polymer-supported
iridium
complex
Cp*Ir@Poly(2,2'-BiBzIm)
was
designed
synthesized
by
coordinative
immobilization
[Cp*IrCl
Язык: Английский
1,6-Conjugate hydrogenation of para-quinone methides to phenol-containing diaryl- and triarylmethanes under atmospheric pressure catalyzed by a metal–ligand bifunctional iridium catalyst
Journal of Catalysis,
Год журнала:
2024,
Номер
unknown, С. 115812 - 115812
Опубликована: Окт. 1, 2024
Язык: Английский
β-Methylation of Primary Alcohols with Methanol Catalyzed by a Metal–Ligand Bifunctional Iridium Catalyst
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(17), С. 12392 - 12400
Опубликована: Авг. 1, 2024
The
development
of
efficient
methods
for
the
direct
introduction
a
methyl
group
into
molecules
is
becoming
increasingly
important.
Herein,
β-methylation
primary
alcohols
with
methanol
has
been
accomplished
under
environmentally
benign
conditions
using
[Cp*Ir(2,2′-bpyO)(H2O)]
as
catalyst.
It
was
found
that
functional
groups
in
ligand
are
crucially
important
activity
iridium
complex.
Furthermore,
mechanistic
research
and
application
potential
our
catalytic
system
also
presented.
Язык: Английский