A Three-Component Reaction of Alkenyl Thianthrenium Salts, Cyclopropanols and Sulfur Dioxide DOI
Xinhua Wang,

Chen Guo,

Minsi Wei

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер 90(1), С. 908 - 912

Опубликована: Дек. 31, 2024

A three-component reaction of alkenyl thianthrenium salts, cyclopropan-1-ols and DABCO·(SO2)2 under catalyst- additive-free conditions, is accomplished. This sulfonylation with the insertion sulfur dioxide works efficiently very mild leading to a wide range 1-substituted vinyl sulfones in moderate good yields. In this protocol, scope generality salts cyclopropyl alcohols demonstrated.

Язык: Английский

Three-Component Reaction of Cyclopropanols, DABSO, and N-(Sulfonyl)acrylamides: Preparation of Sulfone-Bridged 1,7-Dicarbonyl Compounds DOI
Fei Chen, Li Xiao,

Ke-Ying Liu

и другие.

Organic Letters, Год журнала: 2024, Номер 26(34), С. 7170 - 7175

Опубликована: Авг. 19, 2024

A cascade reaction of cyclopropyl alcohols, DABSO (1,4-diazoniabicyclo[2.2.2]octane-1,4-disulfinate), and N-(sulfonyl)acrylamides has been developed. This tandem process went through a cyclopropanol ring opening Michael addition sequence. The γ-keto sulfinate generated from the between serves as nucleophilic reagent, N-(sulfonyl)acrylamide is used acceptor. By utilizing this strategy, multitudinous sulfone-bridged 1,7-dicarbonyl compounds that contain both β-sulfonyl amide unit sulfone skeleton were conveniently synthesized.

Язык: Английский

Процитировано

4
Dialkylation of 1,3-Dienes with Aldehydes and Cyclopropanols toward Homoallylic Alcohols by Dual Photoredox and Chromium Catalysis DOI

Gaochen Xu,

Pei Guan,

Lu Deng

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Апрель 27, 2025

A visible-light-induced three-component coupling of aldehydes, 1,3-dienes, and cyclopropyl alcohols using dual photoredox chromium catalysis is herein described. This efficient protocol achieves the dialkylation 1,3-dienes toward 1,4-disubstituted homoallylic in moderate to good yields with excellent regioselectivity, featuring mild reaction conditions, functional group tolerance, gram-scale synthesis. Mechanistic study suggests that photoinduced sequential ring opening alcohol radical nucleophilic cascade addition are involved catalytic cycle.

Язык: Английский

Процитировано

0
Recent advances in the synthesis of γ-keto sulfones DOI
Cai Zhang

Organic & Biomolecular Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

In this article, the synthesis of γ-keto sulfones over period from 2020 to present will be discussed, and related reaction mechanisms also discussed.

Язык: Английский

Процитировано

0
A Three-Component Reaction of Alkenyl Thianthrenium Salts, Cyclopropanols and Sulfur Dioxide DOI
Xinhua Wang,

Chen Guo,

Minsi Wei

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер 90(1), С. 908 - 912

Опубликована: Дек. 31, 2024

A three-component reaction of alkenyl thianthrenium salts, cyclopropan-1-ols and DABCO·(SO2)2 under catalyst- additive-free conditions, is accomplished. This sulfonylation with the insertion sulfur dioxide works efficiently very mild leading to a wide range 1-substituted vinyl sulfones in moderate good yields. In this protocol, scope generality salts cyclopropyl alcohols demonstrated.

Язык: Английский

Процитировано

1