The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(15), С. 10451 - 10461

Опубликована: Июль 18, 2024

Limonene undergoes a regioselective Pd(II)-catalyzed C(sp2)–H/C(sp2)–H coupling with acrylic acid esters and amides, α,β-unsaturated ketones, styrenes, allyl acetate, affording novel 1,3-dienes. DFT computations gave results in accord the experimental allowed for formulation of plausible mechanism. The postfunctionalization one coupled products was achieved via large-scale Sonogashira reaction conducted under micellar catalysis.

Язык: Английский