Journal of Molecular Liquids, Год журнала: 2024, Номер 415, С. 126401 - 126401
Опубликована: Ноя. 1, 2024
Язык: Английский
European Journal of Organic Chemistry, Год журнала: 2024, Номер 27(45)
Опубликована: Авг. 27, 2024
Abstract Nitroarenes are fundamental feedstocks in the chemical industry. Their relatively inert C−NO 2 bond allows for late‐stage modifications of molecules and exhibits complete orthogonality to reactivity C‐halogen cross‐coupling reactions. The denitrative functionalization nitroarenes holds significant appeal due it avoids use aryl halides, thereby simplifying reaction steps improving atom step economy. Recent progress direct includes palladium‐catalyzed coupling, copper‐catalyzed as well metal‐free one‐pot functionalization. In this review, we provide a concise overview these advancements, detailing features mechanisms. This summary aims highlight versatility efficiency methodologies, offering insights into their potential applications inspiring further research promising area organic synthesis.
Язык: Английский
Процитировано
3
Chemical Communications, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
A method for synthesizing phosphinic amides via hydrogen transfer and oxygen migration through an EDA complex-based cascade reaction is presented.
Язык: Английский
Процитировано
0
Organic Letters, Год журнала: 2025, Номер unknown
Опубликована: Апрель 17, 2025
Reductive hydroamination of stable and readily available nitroarenes with unsaturated hydrocarbons represents practical access to amines. Herein, we report a simple Cu-catalyzed amine synthesis via the reductive inactive diarylacetylenes. A series diarylacetylenes are successfully transformed into secondary amines under mild conditions good functional group tolerance.
Язык: Английский
Процитировано
0
Journal of Molecular Liquids, Год журнала: 2024, Номер 415, С. 126401 - 126401
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
0