Radical-Triggered Bicyclization and Aryl Migration of 1,7-Diynes with Diphenyl Diselenide for the Synthesis of Selenopheno[3,4-c]quinolines DOI
Tian-Shu Zhang, Jiaming He, Yutao Liu

и другие.

Organic Letters, Год журнала: 2025, Номер 27(4), С. 1000 - 1005

Опубликована: Янв. 17, 2025

The translocation of an aryl group from selenium into carbon enabled by the cleavage C-Se bond is reported using nitrogen atom-linked 1,7-diynes and diaryl diselenides as starting materials, leading to various selenophene derivatives in a regioselective manner. This method enables construction two bonds C-C through sequential radical bicyclization 1,2-aryl migration under metal-free conditions. Control experiments mechanistic studies suggest that this reaction proceeds inert C(Ph)-Se bond, facilitating process. transformation one-step conversion simple diverse selenopheno[3,4-c]quinolines via radical-promoted process, holding significant potential for new seleniferous heterocycles.

Язык: Английский

Radical-Triggered Bicyclization and Aryl Migration of 1,7-Diynes with Diphenyl Diselenide for the Synthesis of Selenopheno[3,4-c]quinolines DOI
Tian-Shu Zhang, Jiaming He, Yutao Liu

и другие.

Organic Letters, Год журнала: 2025, Номер 27(4), С. 1000 - 1005

Опубликована: Янв. 17, 2025

The translocation of an aryl group from selenium into carbon enabled by the cleavage C-Se bond is reported using nitrogen atom-linked 1,7-diynes and diaryl diselenides as starting materials, leading to various selenophene derivatives in a regioselective manner. This method enables construction two bonds C-C through sequential radical bicyclization 1,2-aryl migration under metal-free conditions. Control experiments mechanistic studies suggest that this reaction proceeds inert C(Ph)-Se bond, facilitating process. transformation one-step conversion simple diverse selenopheno[3,4-c]quinolines via radical-promoted process, holding significant potential for new seleniferous heterocycles.

Язык: Английский

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