Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 27, 2025

The protocol using only trichloroacetonitrile (CCl3CN) or CCl3CN/methanol to achieve oxidation of sulfides and benzylic C-H bonds in open air was established. Highly selective sulfoxides efficient were realized under clean mild conditions, respectively. main features this are a wide substrate scope, high yields, gram-scale preparation, conversion various pharmaceutical molecules. reactions performed light irradiation, the mechanism demonstrated involve radical process. This provides sustainable straightforward method for bonds.

Язык: Английский