Organic & Biomolecular Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

We have developed a visible-light-driven photocatalytic tandem reaction system to achieve the efficient synthesis of 2-sulfenylated pyrrolo[1,2-α]quinoxalines based on radical addition-cyclization mechanism. Mechanistic studies show that sulfur intermediates generated in directly participate subsequent formation C-S bonds. This strategy has opened up an synthetic pathway for precise C2-sulfur-substituted heterocyclic compounds.

Язык: Английский