Electrochemical Reduction of Co2 on Pure and Doped Cu2o(111) DOI

Hongling Liu,

Di Liu,

Zhichao Yu

и другие.

Опубликована: Янв. 1, 2024

Язык: Английский

Reaction Mechanisms and Applications of Single Atom Catalysts for Thermal-Catalytic Carbon Dioxide Hydrogenation Toward Oxygenates DOI
Fei Wang, Yicheng Liu,

Mengke Peng

и другие.

ACS Catalysis, Год журнала: 2024, Номер 14(21), С. 16434 - 16458

Опубликована: Окт. 23, 2024

Thermo-catalytic CO2 hydrogenation to high-value oxygenates has been regarded as one of the most powerful strategies that can potentially alleviate excessive emissions. However, due high chemical stability and variability pathways, it is still challenging achieve highly active selective hydrogenation. Single atom catalysts (SACs) with ultrahigh metal utilization efficiency extraordinary electronic features have displayed growing importance for thermo-catalytic multiple developed improve performances. Here, we review breakthroughs in developing SACs efficient toward common (CO, HCOOH, CH3OH, CH3CH2OH) following order: first, an analysis reaction mechanisms thermodynamics challenges reactions; second, a summary SAs designed by dividing them into two categories single- dual-sites; third, discussion support effects focus on approaches regulating strong metal–support interaction (MSI). Summarily, current future perspectives develop higher-performance are presented. We expect this bring more design inspiration trigger innovation catalytic evolution materials eventually benefit achievement carbon-neutrality goal.

Язык: Английский

Процитировано

8
Tuning covalent bonding of single transition metal atom doped in S vacant MoS2 for catalytic CO2 reduction reaction product selectivity DOI
Poobodin Mano,

Thanadol Jitwatanasirikul,

Thantip Roongcharoen

и другие.

Applied Surface Science, Год журнала: 2025, Номер 688, С. 162339 - 162339

Опубликована: Янв. 8, 2025

Язык: Английский

Процитировано

1
Orbital hybridizations in single-atom catalysts for electrocatalysis DOI
Luoluo Qi, Jingqi Guan

Science Bulletin, Год журнала: 2025, Номер unknown

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

1
Effect of single atom loading on the CO2 reduction activity of pure and defective W2CO2 MXene DOI

Wenjie Wang,

Cuiping Shao,

Feng Yang

и другие.

Molecular Catalysis, Год журнала: 2024, Номер 569, С. 114550 - 114550

Опубликована: Сен. 19, 2024

Язык: Английский

Процитировано

5
Single-Atom-Embedded Nitrogen-Doped Graphene as Efficient Electrocatalysts for the CO2 Reduction Reaction DOI
Yinlong Tan, Y. Niu,

Xu Ji

и другие.

Langmuir, Год журнала: 2025, Номер unknown

Опубликована: Март 11, 2025

Single-atom catalysts (SACs) have displayed unprecedented activity and selectivity for electrochemical CO2 reduction reaction (CO2RR). Herein, a series of metal single atoms embedded on nitrogen-doped graphene (M–N4G, where M = In, Tl, Ge, Sn, Pb, Sb, Bi) is systematically evaluated as CO2RR electrocatalysts by density functional theory (DFT) calculations. The computational results show that most M–N4G exhibit better over the hydrogen evolution (HER). Ge/Pb–N4G exhibits excellent electrocatalytic performance in generation HCOOH from with low limiting potentials −0.292 −0.306 eV, which surpass vast majority electrocatalysts. Adsorption energy key intermediate *HCOO can be used an effective reactivity descriptor to screen promising catalysts. this work highlight ideal CO2RR.

Язык: Английский

Процитировано

0
Electrochemical reduction of CO2 on pure and doped Cu2O(1 1 1) DOI

Hongling Liu,

Di Liu,

Zhichao Yu

и другие.

Journal of Colloid and Interface Science, Год журнала: 2024, Номер 683, С. 170 - 177

Опубликована: Дек. 10, 2024

Язык: Английский

Процитировано

1
Electrochemical Reduction of Co2 on Pure and Doped Cu2o(111) DOI

Hongling Liu,

Di Liu,

Zhichao Yu

и другие.

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0