S‐scheme MnO2/Co3O4 sugar‐gourd nanohybrids with abundant oxygen vacancies for efficient visible‐light‐driven CO2 reduction DOI
Linfeng Jin,

Hangjing Yu,

Chenhui Wang

и другие.

ChemCatChem, Год журнала: 2024, Номер 16(22)

Опубликована: Авг. 7, 2024

Abstract Converting CO 2 to carbon‐based fuels using solar energy via photocatalysis is a promising approach boost carbon neutrality. However, the solar‐to‐chemical conversion efficiency hampered by interconnected multiple factors including insufficient light absorption, low separation of photogenerated carriers as well complex and sluggish surface reaction kinetics. Herein, we incorporate MnO nanowires Co 3 O 4 hollow polyhedrons with abundant oxygen vacancies (V ) into /Co sugar‐gourd nanohybrids for boosting photoreduction. The not only display strong absorption in visible–near infrared region, but also facilitate terms S‐scheme transfer pathway, supplying electrons reduction reaction. Furthermore, presence V enhances promotes chemical adsorption molecules. In addition, interfacial electronic interaction between contributes activation . Owing synergy pathway , hybrids exhibit greatly enhanced photocatalytic activity towards under irradiation visible comparison bare delivering evolution rate 15.9 umol g −1 h 100 % selectivity.

Язык: Английский

Charge Carrier Dynamics at Heterojunction of Semiconductor Nanoheterostructures for Photocatalytic Solar Fuel Generation DOI Creative Commons

Kai‐An Tsai,

Jung‐Tzu Chang,

Ying‐Chih Pu

и другие.

Advanced Energy and Sustainability Research, Год журнала: 2025, Номер unknown

Опубликована: Фев. 8, 2025

This review summarizes the investigation of semiconductor nanoheterostructures (NHSs) aimed at enhancing efficiency solar fuel generation through various time‐resolved spectroscopic techniques, including transient absorption spectroscopy (TAS), photoluminescence, and in situ TAS. These spectroscopies provide insights into mechanisms exciton charge carrier dynamics heterojunctions optimized NHSs. The significance these techniques underscores necessity for designing effective photocatalysts photoelectrodes applications photocatalytic water splitting carbon dioxide reduction. Finally, current challenges future directions studying NHSs are outlined discussed.

Язык: Английский

Процитировано

0

Boosting CO2 photoreduction over perovskite quantum dots decorated with dispersed ruthenium nanoparticles DOI
Ruizhi Yu, Tao Ma, Xinran Huang

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 687, С. 95 - 104

Опубликована: Фев. 8, 2025

Язык: Английский

Процитировано

0

Charge-transfer dynamics in S-scheme photocatalyst DOI
Liuyang Zhang, Jianjun Zhang, Jiaguo Yu

и другие.

Nature Reviews Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 17, 2025

Язык: Английский

Процитировано

0

Near-Infrared-Responsive Semiconductor Quantum Dots for Solar Photocatalysis DOI

Jen-An Shih,

Shan-Jen Yang, Chun‐Yi Chen

и другие.

ACS Applied Nano Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 16, 2025

Язык: Английский

Процитировано

0

S‐scheme MnO2/Co3O4 sugar‐gourd nanohybrids with abundant oxygen vacancies for efficient visible‐light‐driven CO2 reduction DOI
Linfeng Jin,

Hangjing Yu,

Chenhui Wang

и другие.

ChemCatChem, Год журнала: 2024, Номер 16(22)

Опубликована: Авг. 7, 2024

Abstract Converting CO 2 to carbon‐based fuels using solar energy via photocatalysis is a promising approach boost carbon neutrality. However, the solar‐to‐chemical conversion efficiency hampered by interconnected multiple factors including insufficient light absorption, low separation of photogenerated carriers as well complex and sluggish surface reaction kinetics. Herein, we incorporate MnO nanowires Co 3 O 4 hollow polyhedrons with abundant oxygen vacancies (V ) into /Co sugar‐gourd nanohybrids for boosting photoreduction. The not only display strong absorption in visible–near infrared region, but also facilitate terms S‐scheme transfer pathway, supplying electrons reduction reaction. Furthermore, presence V enhances promotes chemical adsorption molecules. In addition, interfacial electronic interaction between contributes activation . Owing synergy pathway , hybrids exhibit greatly enhanced photocatalytic activity towards under irradiation visible comparison bare delivering evolution rate 15.9 umol g −1 h 100 % selectivity.

Язык: Английский

Процитировано

2