Unveiling Cutting‐Edge Developments in Electrocatalytic Nitrate‐to‐Ammonia Conversion

Advanced Materials, Год журнала: 2024, Номер 36(16)

Опубликована: Янв. 11, 2024

The excessive enrichment of nitrate in the environment can be converted into ammonia (NH

Язык: Английский

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Boosting Nitrate to Ammonia via the Optimization of Key Intermediate Processes by Low‐Coordinated Cu–Cu Sites

Advanced Functional Materials, Год журнала: 2024, Номер 34(24)

Опубликована: Янв. 17, 2024

Abstract The electrochemical reduction of nitrate to ammonia (NO 3 RR) has emerged as a promising but challenging orientation in sustainable development. Cu is one the most effective NO RR catalysts. However, accumulation 2 − on their surface erected bars further improvement efficiency. Herein, Cu‐based electrocatalyst with low‐coordinated atoms (Cu‐LC) synthesized via instantaneous ablation and rapid cooling target by pulse laser proposed new electrocatalyst, which exhibits enhanced activity NH selectivity 97.01%, yield rate 0.624 mmol h −1 cm −2 at −0.8 V versus RHE long‐term durability, superior reported introduction sites upshifts d‐band center near Fermi Level, enhancing adsorption key intermediates ( * , NO) RR, also effectively regulating generation hydrogenation process, inhibiting Cu‐LC surface, thus achieving efficient production. Furthermore, when evaluated cathode material Zn–NO battery, an open circuit voltage 1.3 power density 3.1 mW are achieved Cu‐LC‐based highlighting multifunctional system for production energy supply.

Язык: Английский

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CoSe2 nanowire array enabled highly efficient electrocatalytic reduction of nitrate for ammonia synthesis

Chinese Chemical Letters, Год журнала: 2024, Номер 35(11), С. 110005 - 110005

Опубликована: Май 14, 2024

Язык: Английский

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Mott–Schottky contact synergistically boosts the electroreduction of nitrate to ammonia under low-nitrate concentration

Energy & Environmental Science, Год журнала: 2024, Номер 17(8), С. 2908 - 2920

Опубликована: Янв. 1, 2024

A Mott–Schottky electrocatalyst composed of amorphous Co–B nanochain embedded in CoO x nanosheets was developed for highly efficient conversion NO 3 − -to-NH .

Язык: Английский

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Recent Progress and Perspectives on Transition Metal-Based Electrocatalysts for Efficient Nitrate Reduction

Energy & Fuels, Год журнала: 2024, Номер 38(8), С. 6701 - 6722

Опубликована: Апрель 8, 2024

Electrochemical nitrate reduction is the process of converting into ammonia or nitrogen using electric energy. This saves energy, protects environment, and an important technology for resource recovery water purification. paper examines recent advances in electrochemical research analyzes reaction mechanism path as well influence various factors on through thermodynamic kinetic principles. Second, catalytic performances transition metal electrocatalysts form single metals, alloys, oxides, composites are analyzed detail, which lays foundation rational development new, efficient, stable electrocatalysts. Finally, future directions prospects envisioned.

Язык: Английский

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Boosting nitrate electroreduction to ammonia on atomic Ru-Co pair sites in hollow spinels

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 358, С. 124387 - 124387

Опубликована: Июль 9, 2024

Язык: Английский

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Electrochemical nitrate reduction over bimetallic Pd–Sn nanocatalysts with tunable selectivity toward benign nitrogen

Chemosphere, Год журнала: 2024, Номер 350, С. 141182 - 141182

Опубликована: Янв. 9, 2024

Язык: Английский

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High‐Throughput Ammonia Production from Nitrate Using Liquid Metal Synthesized Bismuth Nano‐Catalyst

Advanced Energy Materials, Год журнала: 2024, Номер 14(28)

Опубликована: Фев. 19, 2024

Abstract The implementation of renewable energy sources to electrify ammonia (NH 3 ) production is identified as a critical approach for achieving successful decarburization in the pursuit more sustainable future. A liquid metal‐based method presented synthesizing bismuth (Bi) nano‐electrocatalysts, enabling efficient and via nitrate electroreduction. Bi‐metal precipitated from gallium metal alloy yields solution‐processable Bi oxide with controllable nanostructures such nanosheets, nanotubes, nanoparticles. Combining nano‐electrocatalysts graphene crystals creates self‐assembling layered electrocatalytic systems. Integrating 3D printing technology allows precise control over geometry, microporosity, number deposited layers scaffold electrode, resulting improved mass transport properties, durability, prevention catalyst detachment. Consequently, rate reaches 400 nmol s −1 cm −2 , Faradaic efficiency 90% current densities exceeding 350 mA . These numbers indicate excellent scalability potential proposed system.

Язык: Английский

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Selective Nitrate Electroreduction to Ammonia on CNT Electrodes with Controllable Interfacial Wettability

Environmental Science & Technology, Год журнала: 2024, Номер 58(16), С. 7228 - 7236

Опубликована: Март 29, 2024

The development of electrocatalysts that can efficiently reduce nitrate (NO

Язык: Английский

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Developing energy-efficient nitrate-to-ammonia flow cells with bifunctional NiFeW-oxide thin-film electrodes made by magnetron sputtering technique

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 354, С. 124137 - 124137

Опубликована: Апрель 27, 2024

Язык: Английский

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