Journal of Materials Chemistry C,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 9, 2024
This
review
systematically
summarized
the
synthesis
approaches
towards
both
polycrystals
and
nanocrystals,
discussed
crystal/electronic
structure,
luminescence
principle,
optimized
strategies
of
lanthanide-based
Cs
3
LnCl
6
metal
halides.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
unknown
Опубликована: Июль 27, 2024
Abstract
Perovskite
light‐emitting
diodes
(PeLEDs)
that
can
be
air‐processed
promises
the
development
of
displaying
optoelectronic
device,
while
is
challenged
by
technical
difficulty
on
both
active
layer
and
hole
transport
(HTL)
caused
unavoidable
humidity
interference.
Here,
we
propose
validate
that,
planting
polymer
brush
with
tailored
functional
groups
in
inorganic
HTL,
provides
unique
bilateral
embedded
anchoring
capable
simultaneously
addressing
n
phases
crystallization
rates
as
well
deteriorated
particulate
surface
defects
HTL.
Exemplified
zwitterionic
polyethyleneimine‐sulfonate
(PEIS)
present
study,
its
implanting
NiO
x
HTL
offers
abundant
nuclei
sites
amino
sulfonate
balance
growth
rate
different
quasi‐2D
perovskite
films.
Moreover,
PEIS
effectively
nailed
interfacial
contact
between
,
reduced
leading
to
enhanced
PLQY
stability
large‐area
blue
film
ambient
air.
By
virtue
these
merits,
work
achieves
first
demonstration
PeLEDs
large
emitting
area
1.0
cm
2
peak
external
quantum
efficiency
(EQE)
2.09
%,
which
comparable
similar
pure‐bromide
fabricated
glovebox.
Ultraviolet
photodetectors
(UV
PDs)
based
on
microcrystals
(MCs)
have
attracted
extensive
attention
due
to
their
outstanding
detection
performance.
Nevertheless,
precise
manipulation
of
the
MCs
still
remains
challenging,
which
may
hinder
mass
processing
and
performance
improvement
UV
PDs.
In
this
work,
a
single
high-quality
Cs
Journal of Materials Chemistry C,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 9, 2024
This
review
systematically
summarized
the
synthesis
approaches
towards
both
polycrystals
and
nanocrystals,
discussed
crystal/electronic
structure,
luminescence
principle,
optimized
strategies
of
lanthanide-based
Cs
3
LnCl
6
metal
halides.