European Journal of Organic Chemistry,
Год журнала:
2022,
Номер
2022(43)
Опубликована: Окт. 14, 2022
Abstract
Allenyl
radicals
are
rarely
employed
as
intermediates
for
the
synthesis
of
allenes
probably
owe
to
lack
convenient
methods
their
generation
and
high
reactivity
short‐lived
allenyl
radicals.
However,
strategies
take
advantage
considered
a
significant
complement
reactions
which
couldn't
proceed
via
an
ionic
pathway.
As
result,
several
important
have
been
developed
in
past
decades.
Herein,
this
review
is
aimed
summarize
recent
advance
involving
by
highlighting
some
outstanding
challenges
confirming
potential
areas
improvement,
would
offer
inspiration
future
studies
Journal of Heterocyclic Chemistry,
Год журнала:
2021,
Номер
59(3), С. 422 - 448
Опубликована: Ноя. 28, 2021
Abstract
In
the
current
extensive
review,
we
pay
special
attention
to
progress
in
synthesis
of
2
H
‐azirine.
Content
is
organized
by
several
main
approaches
for
‐azirines
such
as‐
Neber
rearrangement,
decomposition
vinyl
azides,
oxidative
cyclization
enamines,
ring
contraction
isoxazoles
or
oxazaphospholes,
radical
addition/cyclization
alkynes,
Swern
oxidation
elimination
reactions
aziridine
derivatives,
catalytic
α‐oximino
diazo
compounds,
addition
silyldibromomethyllithium
compounds
nitriles,
carbenes
nitriles
and
via
azirine‐azirine
transformations.
Some
these
open
up
access
new
‐azirine
derivatives
make
already
established
more
convenient.
A
description
methods
using
well‐known
leading
system
are
presented
this
section.
This
review
surveys
various
functionalized
formation
from
exploration
period
present.
European Journal of Organic Chemistry,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 21, 2024
Abstract
A
new
environmentally
friendly
and
efficient
strategy
for
preparing
trifluoromethylated
pyrrolidones
has
been
developed.
The
process
involves
using
visible
light
to
induce
radical
cyclization
of
1,5‐dienes
with
CF
3
SO
2
Na,
resulting
in
excellent
regioselectivity.
This
method
uses
less
expensive
easy‐to‐store
trifluoromethylation
reagents,
making
it
an
attractive
option.
Additionally,
the
can
be
easily
modified
preliminary
mechanistic
studies
have
presented.
Organic Chemistry Frontiers,
Год журнала:
2022,
Номер
9(18), С. 4867 - 4874
Опубликована: Янв. 1, 2022
An
efficient,
transition-metal-free,
photocatalytic
three-component
intermolecular
trifluoromethylation-
gem
-difluoroallylation
of
unactivated
alkenes
has
been
achieved.
European Journal of Organic Chemistry,
Год журнала:
2022,
Номер
2022(43)
Опубликована: Окт. 14, 2022
Abstract
Allenyl
radicals
are
rarely
employed
as
intermediates
for
the
synthesis
of
allenes
probably
owe
to
lack
convenient
methods
their
generation
and
high
reactivity
short‐lived
allenyl
radicals.
However,
strategies
take
advantage
considered
a
significant
complement
reactions
which
couldn't
proceed
via
an
ionic
pathway.
As
result,
several
important
have
been
developed
in
past
decades.
Herein,
this
review
is
aimed
summarize
recent
advance
involving
by
highlighting
some
outstanding
challenges
confirming
potential
areas
improvement,
would
offer
inspiration
future
studies
