The Journal of Organic Chemistry,
Год журнала:
2021,
Номер
86(23), С. 17528 - 17532
Опубликована: Ноя. 18, 2021
Two
visible-light-mediated
O–H
insertion
protocols
involving
oximes
and
aryldiazoacetates
leading
to
different
products
depending
on
the
solvent
employed
are
reported.
In
DCM,
direct
takes
place.
THF,
there
is
additional
incorporation
of
ring-opened
form
this
into
structure
product.
These
metal-free
mild
tolerant
air
moisture.
The
preparation
an
acaricide
has
been
developed
as
example
synthetic
application.
Chemical Reviews,
Год журнала:
2024,
Номер
124(11), С. 7214 - 7261
Опубликована: Май 16, 2024
In
recent
years,
visible
light-induced
reactions
of
diazo
compounds
have
attracted
increasing
attention
in
organic
synthesis,
leading
to
improvement
existing
reactions,
as
well
the
discovery
unprecedented
transformations.
Thus,
photochemical
or
photocatalytic
generation
both
carbenes
and
radicals
provide
milder
tools
toward
these
key
intermediates
for
many
valuable
However,
vast
majority
transformations
represent
new
reactivity
modes
compounds,
which
are
achieved
by
decomposition
photoredox
catalysis.
particular,
use
a
redox-active
photocatalysts
opens
avenue
plethora
radical
reactions.
The
application
methods
led
inaccessible
classical
associated
with
metal
carbenes.
most
cases,
act
sources
but
can
also
serve
acceptors.
Importantly,
described
processes
operate
under
mild,
practical
conditions.
This
Review
describes
this
subfield
compound
chemistry,
particularly
focusing
on
advancements.
Chemical Communications,
Год журнала:
2023,
Номер
59(48), С. 7346 - 7360
Опубликована: Янв. 1, 2023
This
article
discusses
the
photochemistry
of
several
diazo
compounds
undergoing
visible
light-mediated
photolysis
to
generate
free
carbenes
(or
other
highly
reactive
intermediates),
which
can
be
sequentially
trapped
by
different
reacting
partners.
Organic Letters,
Год журнала:
2025,
Номер
27(2), С. 709 - 714
Опубликована: Янв. 7, 2025
Herein,
we
present
a
visible-light-induced
protocol
for
the
synthesis
of
highly
functionalized
oxo-bridged
oxocine
skeletons.
This
method
generates
carbenes
via
ortho-acyl
diazo
compounds,
which
are
rapidly
intercepted
by
oxygen
atom
an
intermolecular
acyl
group
to
form
cyclic
1,3-dipole.
The
in
situ
generated
reactive
1,3-dipole
undergoes
facile
formal
[4
+
3]
cycloaddition
with
alkenyl
pyrazolinone,
yielding
[4.2.1]-oxo-bridged
compounds.
Chinese Journal of Organic Chemistry,
Год журнала:
2021,
Номер
41(12), С. 4565 - 4565
Опубликована: Янв. 1, 2021
Carbene
is
one
of
the
most
important
synthetic
intermediates
in
organic
synthesis.In
past
few
decades,
transition-metal
catalyzed
carbene
transfer
reactions
have
made
remarkable
development.Recently,
visible
light-promoted
transformation
diazo
compounds
through
formation
free
as
key
intermediate
begun
to
rise.The
reaction
only
need
light
sole
energy
source
which
meets
concept
green
chemistry.Since
pioneering
works
developed
by
groups
Diaves
and
Zhou,
photo-promoted
has
attracted
more
attentions.On
basis
previous
work,
latest
progress
this
field
further
improved,
mainly
focuses
on
recent
new
under
irradiation
contributions
reported
from
Chinese
research
group.The
future
development
direction,
well
challenges
prospected.
Green Chemistry,
Год журнала:
2022,
Номер
24(12), С. 4915 - 4920
Опубликована: Янв. 1, 2022
A
convenient
and
eco-friendly
visible-light
promoted
multicomponent
protocol
has
been
developed
for
the
synthesis
of
S
-alkyl
phosphorothioates
by
using
elemental
sulfur
as
cheap
odorless
source.
ACS Catalysis,
Год журнала:
2022,
Номер
12(9), С. 5510 - 5516
Опубликована: Апрель 25, 2022
We
developed
an
efficient
visible-light-mediated
formal
carbene
insertion
reaction
of
1,3-diketones
with
diazoesters
for
the
construction
enantioenriched
1,4-dicarbonyl
compounds
a
quaternary
carbon
center.
Combining
visible
light
and
Brønsted
acid
catalyst,
chiral
were
achieved
in
good
yields
high
enantioselectivities
by
photochemical
transfer
protocol.
Organic Letters,
Год журнала:
2022,
Номер
24(32), С. 6018 - 6023
Опубликована: Авг. 10, 2022
We
disclosed
herein
a
straightforward
photochemical
method
for
the
construction
of
phenanthridines
containing
synthetically
useful
succinate
unit.
The
reaction
occurred
under
visible-light
irradiation
with
cheap
eosin
Y
Na
as
photoredox
catalyst
and
diazo
compound
precursor.
Under
optimal
conditions,
wide
range
were
obtained
in
moderate
to
good
yields.
Note
that
units
final
heterocycles
could
be
easily
transformed
into
many
valuable
structures,
such
γ-butyrolactone,
dihydrofuran-2(3H)-one,
tetrahydrofuran.
Mechanistic
experiments
performed
support
proposed
mechanism.
