Synthesis and Characterization of Post-β-Carbon-Elimination Organopalladium Complexes DOI Creative Commons
Taeho Kang,

Yue Fu,

Rei Matsuura

и другие.

Опубликована: Ноя. 1, 2022

A unique family of N,N,π,C-palladacycles are synthesized from 8-aminoquinoline-coupled nopol derivatives through directed 1,2-migratory insertion in situ generated arylpalladium(II) species followed by β-carbon elimination. These palladacycles have exceptional stability under air and moisture at room temperature, enabling successful isola-tion characterization X-ray crystallography, NMR, high-resolution mass spectrometry. Computational studies shed light on the facile β-alkyl elimination step origins high these post β-carbon-elimination complexes.

Язык: Английский

Synthesis and Characterization of Post-β-Carbon-Elimination Organopalladium Complexes DOI
Taeho Kang, Yue Fu, Rei Matsuura

и другие.

Organometallics, Год журнала: 2022, Номер 42(1), С. 11 - 15

Опубликована: Дек. 20, 2022

A unique family of N,N,π,C-palladacycles are synthesized from 8-aminoquinoline-coupled nopol derivatives through directed 1,2-migratory insertion in situ generated arylpalladium(II) species followed by β-carbon elimination. These palladacycles have exceptional stability under air and moisture at room temperature, enabling successful isolation characterization X-ray crystallography, NMR, high-resolution mass spectrometry. Computational studies shed light on the facile β-alkyl elimination step origins high these post-β-carbon-elimination complexes.

Язык: Английский

Процитировано

5
Ru-Catalyzed Ortho C–H Alkylation of 4-Aryl-pyrrolo[2,3-d]pyrimidines with Diazo Compounds: An Access to Fluorescent Fused Heteroarenes DOI
Jiangrong Wang, Chunfeng Li,

Chunwei Shen

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 9, 2024

A Ru(II)-catalyzed migratory insertion of carbene into

Язык: Английский

Процитировано

0
Palladium-Catalyzed sp3 C–H Acetoxylation of α,α-Disubstituted α-Amino Acids DOI Creative Commons
Atsushi Matsumura, Yoshinosuke Usuki, Tetsuya Satoh

и другие.

Chemistry, Год журнала: 2023, Номер 5(2), С. 1369 - 1377

Опубликована: Июнь 1, 2023

The sp3 C–H acetoxylation at the β-position of α,α-disubstituted α-amino acids proceeds smoothly under palladium catalysis in presence PhI(OAc)2. This reaction provides a straightforward synthetic route to non-natural β-acetoxy-α-amino acids. α-aminocyclopropanecarboxylic acid takes place via ring-opening selectively afford an acyclic γ-acetoxy-α,β-unsaturated amino acid.

Язык: Английский

Процитировано

1
A novel Ag3L2 coordination cage derived from a tripodal oxazoline ligand: synthesis, structure and catalysis DOI
Xuejun Zhang, Lei Wang,

Xiu‐Du Zhang

и другие.

Inorganic Chemistry Communications, Год журнала: 2023, Номер 153, С. 110792 - 110792

Опубликована: Май 3, 2023

Язык: Английский

Процитировано

0
Crystal structure and Hirshfeld surface analysis of 7,7-dimethyl-2-phenyl-3,3a,4,6,7,8,9,9a-octahydro-1H-benzo[f]isoindole-1,5(2H)-dione DOI Creative Commons
Dong Cheng,

Xinlei Gao,

Jia-Ting Huang

и другие.

Acta Crystallographica Section E Crystallographic Communications, Год журнала: 2022, Номер 78(4), С. 373 - 376

Опубликована: Март 10, 2022

The title compound, C 20 H 23 NO 2 , was obtained via the reaction of N -allyl- -phenylacrylamide with 3-iodocyclohex-2-en-1-one using PdCl (PPh 3 ) as a catalyst. compound crystallizes in monoclinic space group P 1 / c . fused-ring system is not planar and five- six-membered rings are trans -fused. molecular geometry partially stabilized by an intramolecular C—H...O hydrogen bond, forming S (6) ring motif. In crystal, molecules linked C—H...π interactions into three-dimensional network. To further analyse intermolecular interactions, Hirshfeld surface analysis performed. results indicate that most important contributions to overall from H...H (65.5%), O...H/H...O (17.5%) C...H/H...C (14.3%) interactions.

Язык: Английский

Процитировано

0
8‐Aminoquinoline DOI

James Roane,

Olafs Daugulis, Thanh Van Le

и другие.

Encyclopedia of Reagents for Organic Synthesis, Год журнала: 2022, Номер unknown, С. 1 - 42

Опубликована: Июль 18, 2022

Процитировано

0
Synthesis and Characterization of Post-β-Carbon-Elimination Organopalladium Complexes DOI Creative Commons
Taeho Kang,

Yue Fu,

Rei Matsuura

и другие.

Опубликована: Ноя. 1, 2022

A unique family of N,N,π,C-palladacycles are synthesized from 8-aminoquinoline-coupled nopol derivatives through directed 1,2-migratory insertion in situ generated arylpalladium(II) species followed by β-carbon elimination. These palladacycles have exceptional stability under air and moisture at room temperature, enabling successful isola-tion characterization X-ray crystallography, NMR, high-resolution mass spectrometry. Computational studies shed light on the facile β-alkyl elimination step origins high these post β-carbon-elimination complexes.

Язык: Английский

Процитировано

0