Chalcogen bonding enabled photosynthesis of aryl selenides from aryl sulfonium salts DOI
Fang Tan, Xiaodi Su,

Qing-Shuang Zhang

и другие.

Organic Chemistry Frontiers, Год журнала: 2023, Номер 11(3), С. 654 - 660

Опубликована: Ноя. 29, 2023

An efficient chalcogen bonding (ChB)-enabled photoactive charge transfer complex protocol for the synthesis of aryl–aryl/aryl–alkyl chalcogenides with aryl sulfonium salts is established.

Язык: Английский

A Practical and Modular Method for Direct C−H Functionalization of the BODIPY Core via Thianthrenium Salts DOI

Xin‐Xin Dong,

Jing‐Guo Liu,

H. Zhang

и другие.

Chemistry - A European Journal, Год журнала: 2024, Номер 30(45)

Опубликована: Май 31, 2024

Direct structural modification of small-molecule fluorophores represents a straightforward and appealing strategy for accessing new fluorescent dyes with desired functionalities. We report herein general efficient visible-light-mediated method the direct C-H functionalization BODIPY, an important chromophore, using readily accessible bench-stable aryl alkenylthianthrenium salts. This practical approach operates at room temperature extraordinary site-selectivity, providing step-economical means to construct various valuable aryl- alkenyl-substituted BODIPY dyes. Remarkably, this protocol encompasses broad substrate scope excellent functional-group tolerance, allows modular synthesis sophisticated symmetrical asymmetrical disubstituted BODIPYs by simply employing different combinations thianthrenium Moreover, late-stage complex drug molecules further highlights potential novel methodology in fluorophore-drug conjugates.

Язык: Английский

Процитировано

1
Efficient late-stage synthesis of quaternary phosphonium salts from organothianthrenium salts by photocatalysis DOI
Jun Liu,

Zhaoyu Feng,

Hanxiang Li

и другие.

Chemical Communications, Год журнала: 2024, Номер 60(66), С. 8760 - 8763

Опубликована: Янв. 1, 2024

A photoactivated approach for the selective late-stage synthesis of quaternary phosphonium salts utilizing organothianthrenium and tertiary phosphines was reported with high yields broad functional group compatibility.

Язык: Английский

Процитировано

1
Light-assisted functionalization of aryl radicals towards metal-free cross-coupling DOI
Huaibo Zhao,

Valentina Dafnae Cuomo,

Wei Tian

и другие.

Nature Reviews Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 15, 2024

Язык: Английский

Процитировано

1
Dehydrogenative Fluorination of gem‐Difluoroalkenes to Access Multi‐Substituted Trifluoromethylalkenes DOI

Manman Wang,

Meng‐Yu Wu,

Rui Ma

и другие.

Advanced Synthesis & Catalysis, Год журнала: 2023, Номер 365(14), С. 2416 - 2421

Опубликована: Июнь 27, 2023

Abstract A dehydrogenative fluorination method is developed to access multi‐substituted trifluoromethylalkenes starting from a variety of gem ‐difluoroalkenes. The reaction proceeds with electrophilic source NFSI only and accommodates wide range functional groups, thus complementing the previously reported protocols. Additionally, visible‐light‐promoted stereoinversion revealed enable E ‐isomer enriched products.

Язык: Английский

Процитировано

3
Chalcogen bonding enabled photosynthesis of aryl selenides from aryl sulfonium salts DOI
Fang Tan, Xiaodi Su,

Qing-Shuang Zhang

и другие.

Organic Chemistry Frontiers, Год журнала: 2023, Номер 11(3), С. 654 - 660

Опубликована: Ноя. 29, 2023

An efficient chalcogen bonding (ChB)-enabled photoactive charge transfer complex protocol for the synthesis of aryl–aryl/aryl–alkyl chalcogenides with aryl sulfonium salts is established.

Язык: Английский

Процитировано

3