Site‐Selective Acylation of Vinylcyclopropanes under Visible‐Light Photocatalysis DOI

Chenna Jagadeesh,

Manveer Patel,

Subhadeep Hazra

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Окт. 17, 2024

Abstract We herein disclose a protocol for linear‐selective ring‐opening acylation of range electron‐poor VCPs with α‐ketoacids by Ir‐photocatalyst. While could be sensitized various radical species generated under different reaction conditions including photo‐redox processes, exploring similar repertoire acyl remains unexplored. Since the linear selective ring opening leads to translocation vinylic olefin into an internal one, terminal addition VCP systems electronically diverse groups present at terminus, permitting formation tailored building blocks.

Язык: Английский

Visible-light-induced photocatalytic iododi(per)fluoroalkylation of 5-amino-N-allyl-1,2,3-triazole-4-carboxamides DOI
Ivanna Yu. Danyliuk,

Sergiy Kemskyi,

Vladyslav Polishchuk

и другие.

Journal of Fluorine Chemistry, Год журнала: 2024, Номер 276, С. 110292 - 110292

Опубликована: Апрель 24, 2024

Язык: Английский

Процитировано

0
Site‐Selective Acylation of Vinylcyclopropanes under Visible‐Light Photocatalysis DOI

Chenna Jagadeesh,

Manveer Patel,

Subhadeep Hazra

и другие.

Asian Journal of Organic Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Окт. 17, 2024

Abstract We herein disclose a protocol for linear‐selective ring‐opening acylation of range electron‐poor VCPs with α‐ketoacids by Ir‐photocatalyst. While could be sensitized various radical species generated under different reaction conditions including photo‐redox processes, exploring similar repertoire acyl remains unexplored. Since the linear selective ring opening leads to translocation vinylic olefin into an internal one, terminal addition VCP systems electronically diverse groups present at terminus, permitting formation tailored building blocks.

Язык: Английский

Процитировано

0