
Frontiers in Chemistry, Год журнала: 2024, Номер 12
Опубликована: Сен. 6, 2024
Trifluoromethyl (CF
Язык: Английский
Frontiers in Chemistry, Год журнала: 2024, Номер 12
Опубликована: Сен. 6, 2024
Trifluoromethyl (CF
Язык: Английский
Organic Letters, Год журнала: 2024, Номер 26(38), С. 8149 - 8153
Опубликована: Сен. 16, 2024
Indole and quinoline structures are present in numerous biologically active molecules, making the synthesis of their glycosylation products a subject extensive research interest drug development. Here, we report photoredox strategy for
Язык: Английский
Процитировано
3Chinese Journal of Organic Chemistry, Год журнала: 2025, Номер 45(4), С. 1379 - 1379
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Июнь 2, 2025
A metal-free electrophilic phosphination protocol utilizing silyl enol ethers as soft carbon nucleophiles has been developed under Tf2O/DMSO-mediated conditions. This approach enables convenient access to a diverse range of β-ketophosphine oxides mild reaction The broad substrate scope, scalability, and potential for further synthetic applications highlight the practical utility this method. development method also expands scope umpolung strategies.
Язык: Английский
Процитировано
0Organic Chemistry Frontiers, Год журнала: 2023, Номер 11(3), С. 796 - 801
Опубликована: Дек. 5, 2023
A straightforward and practical strategy for decarboxylphosphatization of N -aryl glycines to access α-amino phosphine oxides, enabled by visible-light photoredox catalysis in the absence metal, base, has been described.
Язык: Английский
Процитировано
8Asian Journal of Organic Chemistry, Год журнала: 2024, Номер 13(4)
Опубликована: Фев. 26, 2024
Abstract A convenient visible–light–promoted phosphorylation reaction of α‐diazoesters with H‐phosphine oxides for the preparation ( Z )‐phosphinic hydrazones has been explored. This could be performed under mild conditions to afford a series in moderate good yields through photoisomerization C=N bond.
Язык: Английский
Процитировано
2New Journal of Chemistry, Год журнала: 2024, Номер 48(20), С. 9000 - 9003
Опубликована: Янв. 1, 2024
A photocatalyst-free hydrothiolation reaction of aromatic gem -difluoroalkenes was developed under the irradiation blue light in dimethyl carbonate as a green solvent.
Язык: Английский
Процитировано
2Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(21), С. 4249 - 4253
Опубликована: Янв. 1, 2024
A Cu
Язык: Английский
Процитировано
2The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(14), С. 10223 - 10233
Опубликована: Июнь 28, 2024
A photo-induced cascade sulfone alkylation/cyclization of 2-isocyanoaryl thioethers is explored. This visible-light-triggered reaction not only occurs under extremely mild conditions but also does require the presence a photosensitizer. The photocatalytic process triggered by photochemical activity in situ-generated electron donor–acceptor complexes, arising from association and α-iodosulfones. radical pathway was confirmed UV–vis spectroscopy, trapping, Job's plot, on/off irradiation experiments.
Язык: Английский
Процитировано
2The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(16), С. 11659 - 11664
Опубликована: Авг. 1, 2024
Herein, we report a direct phosphorylation of the C(sp3)–H bond 3,4-dihydroquinoxalin-2(1H)-ones using oxygen as green oxidant under visible light at room temperature. This transformation was readily accomplished in absence metal and photosensitizer to construct new C(sp3)–P bonds provide series phosphonylated dihydroquinoxalin-2-ones good excellent yields. approach opens straightforward environmentally friendly access 3-phosphoryl quinoxalin-2-ones derivatives.
Язык: Английский
Процитировано
2Tetrahedron, Год журнала: 2024, Номер 168, С. 134352 - 134352
Опубликована: Ноя. 1, 2024
Язык: Английский
Процитировано
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