Palladium-catalyzed radical arylation of N-hydroxyphthalimides with triphenyl phosphites as an unusual arylating agent via C(sp²)–O bond cleavage

Organic Chemistry Frontiers, Год журнала: 2023, Номер 11(4), С. 1069 - 1075

Опубликована: Дек. 20, 2023

An approach has been developed for producing aryl radical intermediates by utilizing readily accessible triphenyl phosphite as the precursor in a Pd-catalyst system under air conditions. Moreover, possible mechanism was proposed.

Язык: Английский

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Metal-free construction of diverse 1,2,4-triazolo[1,5-a]pyridines on water

Chinese Chemical Letters, Год журнала: 2024, Номер 36(1), С. 109755 - 109755

Опубликована: Март 9, 2024

Язык: Английский

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NaIO4/Air-Initiated Phosphorylation of Alcohols with H-Phosphine Oxides for the Construction of P(O)-O Bonds in Water

Organic & Biomolecular Chemistry, Год журнала: 2024, Номер 22(36), С. 7518 - 7523

Опубликована: Янв. 1, 2024

A facile and efficient protocol for P(O)-O bond formation was discovered through NaIO

Язык: Английский

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Direct Synthesis of N-Substituted Phosphinecarboxamides from [TBA][P(SiCl3)2] and Isonitriles

Synlett, Год журнала: 2024, Номер unknown

Опубликована: Авг. 29, 2024

Abstract In this investigation, N-substituted phosphinecarboxamides were produced through the reaction of [TBA][P(SiCl3)2] with isonitriles. This method capitalizes on flexibility isonitriles as a source both nitrogen and carbonyl groups, offering novel route to generation PH2-type compounds. approach is characterized by rapid times, simple procedural requirements, compatibility diverse array substrates, conversion into organic phosphorus Additionally, we systematically studied mechanism isonitrile controlled experiments density functional theory (DFT) calculations.

Язык: Английский

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Photocatalytic fluoroalkylation by ligand-to-metal charge transfer

Frontiers in Chemistry, Год журнала: 2024, Номер 12

Опубликована: Сен. 6, 2024

Trifluoromethyl (CF

Язык: Английский

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