Iron(I) and Iron(II) Boxmi Pincer Complexes: Coordination Chemistry and Catalytic Hydroboration of Nitriles
David Bürgy,
Clemens K. Blasius,
Tim Bruckhoff
и другие.
Organometallics,
Год журнала:
2025,
Номер
unknown
Опубликована: Июнь 4, 2025
Язык: Английский
Au Nanoparticle-Catalyzed Double Hydrosilylation of Nitriles by Diethylsilane
Organic & Biomolecular Chemistry,
Год журнала:
2024,
Номер
22(26), С. 5346 - 5352
Опубликована: Янв. 1, 2024
We
present
the
first
example
of
Au-catalyzed
reduction
nitriles
into
primary
amines.
In
contrast
to
monohydrosilanes
which
are
completely
unreactive,
diethylsilane
(a
dihydrosilane)
is
capable
reducing
aryl
or
alkyl
amines
under
catalysis
by
Au
nanoparticles
supported
on
TiO
Язык: Английский
Cobalt-Catalyzed Borylative Reduction of Azobenzenes to Hydrazobenzenes via a Diborylated-Hydrazine Intermediate
The Journal of Organic Chemistry,
Год журнала:
2024,
Номер
89(13), С. 9265 - 9274
Опубликована: Июнь 20, 2024
Cobalt-catalyzed
borylative
reduction
of
azobenzenes
using
pinacolborane
is
developed.
The
simple
cobalt
chloride
catalyst
and
reaction
conditions
make
this
protocol
attractive
for
hydrazobenzene
synthesis.
This
shows
good
functional
group
compatibility
can
be
readily
scaled
up
to
the
gram
scale.
Preliminary
mechanistic
studies
clarified
proton
source
hydrazine
products.
cobalt-catalyzed
azobenzene
provides
a
practical
prepare
synthetically
useful
diborylated
hydrazines.
Язык: Английский