Light-Induced Reactivity of Nucleophilic Siloxycarbene with Heterocumulenes: Synthesis of α-Ketoamides, Hydantoins, Oxoacetamidines, and Amides DOI
Mohammad Saleem,

Pandey Abhishek,

Dongari Yadagiri

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 25, 2024

We report the reactivity of in situ-generated nucleophilic siloxycarbenes from acylsilanes via 1,2-Brook rearrangement presence visible light with heterocumulenes. This method significantly advances conventional use electrophilic carbenes stabilized by metal catalysts and harsh reaction conditions. The was explored isocyanates, carbodiimides,

Язык: Английский

Radical Brook rearrangement: past, present, and future DOI
Yunxiao Zhang, Gang Zhou, Shanshan Liu

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review aims to provide an overview of radical Brook rearrangement, which is organized by grouping three type reactive species generated via the unique rearrangement process.

Язык: Английский

Процитировано

1
Fluoroalkylacylsilanes as Novel Ambiphilic Donor–Acceptor Carbene Precursors DOI
Xiao Shen

Accounts of Chemical Research, Год журнала: 2025, Номер unknown

Опубликована: Апрель 25, 2025

Язык: Английский

Процитировано

0
Visible-light-induced organocatalyzed C(sp2)-H bond functionalization of 1,3-azoles with trifluoroacetylsilanes DOI
Zhengyu Li,

Zeguo Zhang,

Zhihan Zhang

и другие.

Science China Chemistry, Год журнала: 2024, Номер 67(11), С. 3662 - 3668

Опубликована: Сен. 18, 2024

Язык: Английский

Процитировано

3
Generation of Nickel Siloxycarbene Complexes from Acylsilanes for the Catalytic Synthesis of Silyl Enol Ethers DOI

Akihisa Matsuura,

Yuri Ito,

Tetsuya Inagaki

и другие.

ACS Catalysis, Год журнала: 2024, Номер unknown, С. 18216 - 18222

Опубликована: Ноя. 25, 2024

A catalytic protocol has been developed to access Fischer carbene nickel complexes using acylsilanes as stable and readily available precursors. The as-generated exhibit versatile reactivity, including cyclopropanation with alkenes, α-C–H insertion reactions, two-component C–H addition norbornene, which demonstrates the broad utility of nickel(0)/acylsilane system for applications complexes.

Язык: Английский

Процитировано

1
Addition of Organosilicon Reagents to Unsaturated Bonds DOI
Yasunori Minami

Elsevier eBooks, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0
Light-Induced Reactivity of Nucleophilic Siloxycarbene with Heterocumulenes: Synthesis of α-Ketoamides, Hydantoins, Oxoacetamidines, and Amides DOI
Mohammad Saleem,

Pandey Abhishek,

Dongari Yadagiri

и другие.

Organic Letters, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 25, 2024

We report the reactivity of in situ-generated nucleophilic siloxycarbenes from acylsilanes via 1,2-Brook rearrangement presence visible light with heterocumulenes. This method significantly advances conventional use electrophilic carbenes stabilized by metal catalysts and harsh reaction conditions. The was explored isocyanates, carbodiimides,

Язык: Английский

Процитировано

0