Borate-mediated aryl polyfluoroalkoxylation under transition-metal-free conditions

Chemical Communications, Год журнала: 2024, Номер 60(76), С. 10552 - 10555

Опубликована: Янв. 1, 2024

We report boron-intermediary ligand transfer of diaryliodonium salt, synthesizing polyfluorolalkyl aryl ethers in the absence transition metal catalyst or base.

Язык: Английский

Transition-metal-free dibenzoxazepinone synthesis by hypervalent iodine-mediated chemoselective arylocyclizations of N-functionalized salicylamides

Chemical Communications, Год журнала: 2024, Номер unknown

Опубликована: Дек. 31, 2024

This study reports the chemoselective arylocyclizations utilizing two distinct types of hypervalent iodine reagents, resulting in synthesis dibenzoxazepinones under transition-metal-free conditions.

Язык: Английский