The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Дек. 22, 2024
We have developed a simple and straightforward synthesis of chiral
Язык: Английский
The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Дек. 22, 2024
We have developed a simple and straightforward synthesis of chiral
Язык: Английский
The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Фев. 6, 2025
We report a domino reaction of 2-(2-acylvinyl)indoles as well the corresponding pyrroles with styrylsulfonium salts under mild conditions, affording cyclopropamitosene analogues in high yields and complete diastereoselectivity. A wide range (E)-β-hetaryl-α,β-unsaturated ketones were successfully employed for synthesis potentially bioactive cyclopropa[3,4]pyrrolo[1,2-a]indoles related cyclopropa[a]pyrrolizines, demonstrating versatility developed method. In contrast, (Z)-isomers substrates fail to give derivatives but undergo cyclopropanation terminal methyl group.
Язык: Английский
Процитировано
0The Journal of Organic Chemistry, Год журнала: 2024, Номер unknown
Опубликована: Дек. 22, 2024
We have developed a simple and straightforward synthesis of chiral
Язык: Английский
Процитировано
0