Electrochemical Conversion of N‐Sulfinylamines to Sulfonimidoyl Fluorides DOI Open Access

Fang‐Ling Gao,

Xinglei He,

Bin Zhao

и другие.

Chinese Journal of Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

Comprehensive Summary The invention of novel linkers is a long‐lasting task in the area sulfur(VI) fluoride exchange reaction (SuFEx). Compared with most frequently investigated sulfonyl fluorides, synthetic accessibility toward its mono‐aza isostere, i.e. , sulfonimidoyl fluorides still limited. Herein, we report an electrochemical carbonfluorination readily available N ‐sulfinylamines to access various aryl and alkyl fluorides. transformation characterized by ready availability starting materials, mild conditions, obviating metal catalysts chemical oxidants.

Язык: Английский

Regioselectively electrochemical Csp3-H alkoxylation for functionalized indanone DOI Creative Commons

Xue-Yang Guo,

B. Yao, Li‐Rong Wen

и другие.

Green Synthesis and Catalysis, Год журнала: 2024, Номер unknown

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

1

Electrochemical Conversion of N‐Sulfinylamines to Sulfonimidoyl Fluorides DOI Open Access

Fang‐Ling Gao,

Xinglei He,

Bin Zhao

и другие.

Chinese Journal of Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

Comprehensive Summary The invention of novel linkers is a long‐lasting task in the area sulfur(VI) fluoride exchange reaction (SuFEx). Compared with most frequently investigated sulfonyl fluorides, synthetic accessibility toward its mono‐aza isostere, i.e. , sulfonimidoyl fluorides still limited. Herein, we report an electrochemical carbonfluorination readily available N ‐sulfinylamines to access various aryl and alkyl fluorides. transformation characterized by ready availability starting materials, mild conditions, obviating metal catalysts chemical oxidants.

Язык: Английский

Процитировано

1