Relative Cycloaddition Rates of Alkyne-Equivalent Dienophiles DOI

Tucker J. Hamilton,

Christopher M. Beaudry

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 3, 2025

Alkyne-equivalent dienophiles are strategically important coupling partners in Diels-Alder reactions. They particularly useful cascade bond-forming processes that begin with cycloadditions. A systematic rate study for the cycloaddition of several alkyne and alkyne-equivalent is presented, showing relative reaction rates these vary over multiple orders magnitude.

Язык: Английский

Relative Cycloaddition Rates of Alkyne-Equivalent Dienophiles DOI

Tucker J. Hamilton,

Christopher M. Beaudry

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 3, 2025

Alkyne-equivalent dienophiles are strategically important coupling partners in Diels-Alder reactions. They particularly useful cascade bond-forming processes that begin with cycloadditions. A systematic rate study for the cycloaddition of several alkyne and alkyne-equivalent is presented, showing relative reaction rates these vary over multiple orders magnitude.

Язык: Английский

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