The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 29, 2025

This report presents a method for the synthesis of 2-aroyl cyclobutanones via reaction in situ-generated cyclopropanones with acyl sulfonium ylides representing formal carbene insertion into cyclopropanones. The is highly stereoselective case 2-substituted cyclopropanones, and thus obtained are well suited to α-alkylation, offering versatile synthetic applications.

Язык: Английский