Chinese Journal of Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Май 19, 2025
Comprehensive Summary Visible light‐induced transformation of CO 2 and CS into value‐added products has attracted worldwide attention because it mimics nature. In this context, although visible‐light‐induced direct synthesis dithiocarbamates carbamates employing SO as a C1 source been reported, all these reactions are limited to the preparation S ‐alkyl mono‐dithiocarbamates O mono‐carbamates. Herein, we report visible‐light photoredox‐catalyzed multicomponent reaction diazosulfonium triflates with amines or . Mechanistic studies indicate that diazomethyl radicals might be generated key intermediates, thus providing direction for application other radical acceptors.
Язык: Английский