Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Апрель 7, 2025

Allyl thioesters, thiocarbonates, thiocarbamates, and thiocyanates are shown to undergo rhodium-catalyzed addition of carbene groups, generated from diazo compounds, afford S-acyl sulfonium ylides that [2,3] sigmatropic rearrangement. Competing side reactions such as cyclopropanation [1,2] acyl shifts not observed. The reaction works with a variety sulfur functional including thiocyanates, affording densely functionalized products. well trimethylsilyldiazomethane (TMSD) α-aryl diazoesters.

Язык: Английский