Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Фев. 21, 2025

A metal-free, visible-light-induced NHC-catalyzed multiple-component reaction involving aldehydes and aryl thianthrenium salts for the carboacylation of alkenes is reported. In this reaction, NHC-activated afforded Breslow intermediates, which reduced generated radicals. The resulting radicals underwent radical addition reactions to yield arylacylation products, in presence iodoalkane, participated halogen atom transfer process generate alkyl facilitate olefin alkylacylation.

Язык: Английский