Chelating-Group-Assisted C(sp2)–O Reductive Elimination at the Gold(III) Center DOI
Avishek Das, Sadhana Tripathi, Lisa Roy

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 1, 2025

Herein, we demonstrate chelating-group-assisted C(sp2)-O reductive elimination at gold(III) centers. Detailed stoichiometric studies highlighted the importance of a chelating group for achieving successful C-O elimination, paving way development catalytic version. The mechanistic investigations, including control experiments, 31P NMR, mass spectrometry, and density functional theory (DFT) studies, suggested that synergistic effect ligand creates highly coordinated environment around Au(III) center to facilitate bond-forming reaction.

Язык: Английский

Chelating-Group-Assisted C(sp2)–O Reductive Elimination at the Gold(III) Center DOI
Avishek Das, Sadhana Tripathi, Lisa Roy

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 1, 2025

Herein, we demonstrate chelating-group-assisted C(sp2)-O reductive elimination at gold(III) centers. Detailed stoichiometric studies highlighted the importance of a chelating group for achieving successful C-O elimination, paving way development catalytic version. The mechanistic investigations, including control experiments, 31P NMR, mass spectrometry, and density functional theory (DFT) studies, suggested that synergistic effect ligand creates highly coordinated environment around Au(III) center to facilitate bond-forming reaction.

Язык: Английский

Процитировано

0