Photocatalytic Iminothiolation of Alkenes via Monothiocarbonate Oxime Esters
ACS Catalysis,
Год журнала:
2025,
Номер
unknown, С. 6731 - 6738
Опубликована: Апрель 10, 2025
Язык: Английский
Photo-Thiocyanoamination of π- and σ-Bonds: Reagent Development and Synthetic Applications
The Journal of Organic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 29, 2025
1,2-Thiocyanoamines
make
up
a
class
of
important
structural
motifs
that
are
found
in
number
bioactive
molecules
and
precursors
to
many
more.
Despite
their
synthetic
significance,
expedient
access
this
difunctionalization
is
rare.
Herein,
the
development
thiocyanoimination
reagent
disclosed,
taking
advantage
photomediated
energy
transfer
phenomena
for
facile
alkenes.
The
strategy
was
be
viable
σ-bonds
as
well,
providing
generalized
accessing
small
infused
with
amine
-SCN.
Язык: Английский
Photosensitized Imino-Sulfamoylation of Alkenes with Oxime Carbamates
Ai-Lian Wang,
Huan-Huan Zhao,
Haowen Jiang
и другие.
Organic Letters,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 1, 2025
In
this
study,
we
have
devised
a
strategy
that
employs
oxime
carbamate
as
bifunctional
diamination
reagent
in
combination
with
SO2
to
realize
imino-sulfamoylation
of
alkenes.
This
protocol
is
characterized
by
its
mild
conditions,
operational
simplicity,
and
metal-free
nature,
while
demonstrating
broad
functional
group
tolerance
for
Furthermore,
the
application
method
provides
an
accessible
route
diverse
range
β-amino
sulfonamide
derivatives.
Язык: Английский