Electrochemical Aryl(alkyl)thiolation on α-C–H Bond of Ethers to Access O,S-Acetals DOI
Mengyun Wu, Mingqi Chen, Wenhui Wang

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 21, 2025

The efficient construction of a C-S bond is one the important topics in organic synthesis. In this work, cross-dehydrogenative coupling reaction between ether and thiophenols or thiols under electrochemical conditions was studied, acetal-O,S products were obtained moderate to good yields. A free radical mechanism proposed. provided simple protocol for formation C(sp3)-S bonds transition-metal- chemical oxidant-free conditions, will have application prospect synthesis drug

Язык: Английский

Electrochemical Aryl(alkyl)thiolation on α-C–H Bond of Ethers to Access O,S-Acetals DOI
Mengyun Wu, Mingqi Chen, Wenhui Wang

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 21, 2025

The efficient construction of a C-S bond is one the important topics in organic synthesis. In this work, cross-dehydrogenative coupling reaction between ether and thiophenols or thiols under electrochemical conditions was studied, acetal-O,S products were obtained moderate to good yields. A free radical mechanism proposed. provided simple protocol for formation C(sp3)-S bonds transition-metal- chemical oxidant-free conditions, will have application prospect synthesis drug

Язык: Английский

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