Electrophilic (Hetero)Arene C–H Nitration by Ferric Nitrate Nonahydrate in Hexafluoroisopropanol DOI

Yuzhu Zheng,

Zongyi Liu,

Ying Zhu

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 15, 2025

In this article, we provide an extended substrate scope and more detailed mechanistic studies of operationally simple generally applicable arene nitration that previously reported. This method utilizes safe inexpensive Fe(NO3)3•9H2O as the nitro source in easily recyclable HFIP obviates need for corrosive acids (HNO3 + H2SO4). As a result, speculated it could serve effective substitute traditional mixed acid approach under most scenarios due to its operational simplicity. A general guidance application was provided.

Язык: Английский

Electrophilic (Hetero)Arene C–H Nitration by Ferric Nitrate Nonahydrate in Hexafluoroisopropanol DOI

Yuzhu Zheng,

Zongyi Liu,

Ying Zhu

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 15, 2025

In this article, we provide an extended substrate scope and more detailed mechanistic studies of operationally simple generally applicable arene nitration that previously reported. This method utilizes safe inexpensive Fe(NO3)3•9H2O as the nitro source in easily recyclable HFIP obviates need for corrosive acids (HNO3 + H2SO4). As a result, speculated it could serve effective substitute traditional mixed acid approach under most scenarios due to its operational simplicity. A general guidance application was provided.

Язык: Английский

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