Visible-Light-Mediated Perfluoroalkylation/Thioetherification of [1.1.1]Propellane under Photocatalyst-Free Conditions DOI
Jiabin Shen,

Liangfeng Yang,

Ge Kai

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 29, 2025

Perfluoroalkyl-functionalized bicyclo[1.1.1]pentane (BCP) derivatives have garnered significant attention in pharmaceuticals due to their special physicochemical property; however, establishing convenient synthetic protocols for these fluorinated molecular frameworks continues present substantial methodological challenges. Herein, we report a photocatalyst and additive-free perfluoroalkylation/thioetherification of [1.1.1] propellane with disulfide ether perfluoroalkyl iodines. Such photochemistry methodology utilizing an electron donor-acceptor (EDA) complex offers green novel way obtain various BCP containing thioether groups good functional group tolerance.

Язык: Английский

Photo-induced aerobic cross-coupling of quinoxalin-2(1H)-ones with electron-rich thiophenes DOI
Wei Huang, Tong Wang, Shuying Chen

и другие.

Organic & Biomolecular Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Herein, an efficient aerobic cross-coupling of quinoxazolines with electron-rich thiophenes was presented. It's easy and effective access to 3-thiophenyl quinoxalinones without external photo-catalyst or transition-metal catalyst.

Язык: Английский

Процитировано

0
Visible-Light-Mediated Perfluoroalkylation/Thioetherification of [1.1.1]Propellane under Photocatalyst-Free Conditions DOI
Jiabin Shen,

Liangfeng Yang,

Ge Kai

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Май 29, 2025

Perfluoroalkyl-functionalized bicyclo[1.1.1]pentane (BCP) derivatives have garnered significant attention in pharmaceuticals due to their special physicochemical property; however, establishing convenient synthetic protocols for these fluorinated molecular frameworks continues present substantial methodological challenges. Herein, we report a photocatalyst and additive-free perfluoroalkylation/thioetherification of [1.1.1] propellane with disulfide ether perfluoroalkyl iodines. Such photochemistry methodology utilizing an electron donor-acceptor (EDA) complex offers green novel way obtain various BCP containing thioether groups good functional group tolerance.

Язык: Английский

Процитировано

0