ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown
Опубликована: Март 14, 2025
Lead-free halide perovskite (LFHP) materials have recently received a lot of attention in optoelectronic applications due to their low toxicity and outstanding optical characteristics. Simultaneously, the increased thrust for flexible, wearable, lightweight devices is driving improvements sensor actuator technology. In this context, flexible piezoelectric polymer composites based on LFHPs are gaining popularity exceptional piezoelectric, pyroelectric, ferroelectric, traits. Thus, investigation presents long-term stable lead-free rubidium copper chloride (Rb2CuCl3)-based poly(vinylidene fluoride) composites. The optimized PVDF/Rb2CuCl3 composite yields ∼92.4% electroactive phase PVDF. Interfacial interactions between PVDF Rb2CuCl3 played pivotal role β-phase transformation, resulting improved stability. A nanogenerator (PENG) has been fabricated employing mechanical energy harvesting biophysiological motion monitoring, demonstrating potential healthcare industry. Piezoelectric Energy Harvester (PEH) with PRCC_2.5 (PVDF 2.5 wt % Rb2CuCl3) outperformed other composites, maximum open-circuit voltage (Voc) ∼51.7 V short-circuit current (Isc) ∼4.6 μA. pristine PVDF-based device (PEH 0) had inferior performance, Voc ∼12 an Isc ∼0.5 PEH exhibited charge ∼126 nC, which far higher than 0 corresponding was ∼7 nC. Furthermore, during periodic application force ∼5 N, stability durability were evaluated. 10,250 compression cycles used measure electrical output device. Remarkably, following cycles, there no discernible drop (∼16 V). addition, photodetector developed investigate piezo-phototronic effect, displaying quick photoswitching behavior rise decay periods ∼3.22 ∼5.48 s, respectively. These findings demonstrate that significant as signal-modulated piezoresponsive wearable sensor.
Язык: Английский