Molecules,
Год журнала:
2022,
Номер
27(18), С. 5891 - 5891
Опубликована: Сен. 11, 2022
Energetic
materials
constitute
one
of
the
most
important
subtypes
functional
used
for
various
applications.
A
promising
approach
construction
novel
thermally
stable
high-energy
is
based
on
an
assembly
polynitrogen
biheterocyclic
scaffolds.
Herein,
we
report
design
and
synthesis
a
new
series
high-nitrogen
energetic
salts
comprising
C-C
linked
6-aminotetrazinedioxide
hydroxytetrazole
frameworks.
Synthesized
were
thoroughly
characterized
by
IR
multinuclear
NMR
spectroscopy,
elemental
analysis,
single-crystal
X-ray
diffraction
differential
scanning
calorimetry.
As
result
vast
amount
formed
intra-
intermolecular
hydrogen
bonds,
prepared
ammonium
amino-1,2,4-triazolium
are
have
good
densities
1.75-1.78
g·cm-3.
All
synthesized
compounds
show
high
detonation
performance,
reaching
that
benchmark
RDX.
At
same
time,
as
compared
to
RDX,
investigated
less
friction
sensitive
due
net
bonds.
Overall,
reported
represent
perspective
subclass
secondary
explosives
unveil
further
opportunities
next-generation
materials.
FirePhysChem,
Год журнала:
2021,
Номер
2(2), С. 83 - 139
Опубликована: Окт. 1, 2021
Energetic
material
is
a
very
essential
company
of
compounds,
widely
used
in
various
fields,
primarily
the
military
industry
and
space
technologies.
These
compounds
are
unique
that
they
capable
instantly
decomposing
to
release
enormous
energy.
The
chemical
diversity
energetic
organic
constantly
increasing
through
combination
high-nitrogen
frameworks
explosophoric
groups,
which
follows
overall
trend
interest
their
chemistry
applications.
scientific
community
looking
for
more
powerful
less
sensitive
external
impulses
both
civilian
use.
Herein,
detailed
overview
regarding
classic
novel
groups
frameworks,
as
well
description
selected
synthesis
target
has
been
given
time
period
since
2010.
physical
properties
performances
benchmark
prospective
also
collected.
Journal of Materials Chemistry A,
Год журнала:
2022,
Номер
10(20), С. 11054 - 11073
Опубликована: Янв. 1, 2022
The
abundant
dataset
of
detonation
parameters
for
energetic
materials
is
reported,
empirical
and
thermodynamic
calculation
methods
are
benchmarked,
implications
design
novel
promising
compounds
provided.
Russian Chemical Reviews,
Год журнала:
2024,
Номер
93(7), С. RCR5125 - RCR5125
Опубликована: Июль 1, 2024
The
chemistry
of
heterocyclic
compounds
has
traditionally
been
and
remains
a
bright
area
chemical
science
in
Russia.
This
is
due
to
the
fact
that
many
heterocycles
find
widest
application.
These
are
key
structural
fragments
most
drugs,
plant
protection
agents.
Many
natural
also
derivatives
heterocycles.
At
present,
more
than
half
hundreds
millions
known
collective
review
devoted
achievements
Russian
chemists
this
field
over
last
15–20
years.
presents
leading
heterocyclists
representing
both
RAS
institutes
university
science.
It
worth
noting
wide
scope
review,
terms
geography
author
teams,
covering
whole
our
large
country,
diversity
research
areas.
Practically
all
major
types
represented
review.
special
attention
focused
on
practical
applications
design
new
drugs
biologically
active
compounds,
high-energy
molecules,
materials
for
organic
electronics
photovoltaics,
ligands
coordination
chemistry,
other
rapidly
developing
advances
would
not
be
possible
without
development
fundamental
transformations
chemistry.<br>
Bibliography
—
2237
references.
ACS Applied Materials & Interfaces,
Год журнала:
2023,
Номер
15(3), С. 4144 - 4151
Опубликована: Янв. 11, 2023
The
introduction
of
groups
with
high
enthalpies
formation
can
effectively
improve
the
detonation
performance
compounds.
A
series
novel
energetic
compounds
(10-13)
formation,
density,
and
nitrogen-oxygen
content
were
designed
synthesized
by
combining
gem-polynitromethyl,
1,2,4-oxadiazole,
furoxan,
azo
groups.
All
new
thoroughly
characterized
IR,
NMR,
elemental
analysis,
differential
scanning
calorimetry.
Compounds
10
11
also
further
single-crystal
X-ray
diffraction.
Compound
has
density
(1.93
g
cm-3),
enthalpy
(993.5
kJ
mol-1),
velocity
(9411
m
s-1),
heat
(6889
kg-1)
is
a
potentially
excellent
secondary
explosive.
Energetic Materials Frontiers,
Год журнала:
2021,
Номер
2(1), С. 3 - 13
Опубликована: Янв. 14, 2021
In
recent
years,
the
development
of
novel
advanced
high-energy
density
materials
has
significantly
shifted
toward
nitrogen-containing
heterocyclic
derivatives,
which
demonstrate
a
great
potential
for
multipurpose
application
patterns.
Among
known
heterocycles
hydroxytetrazole
is
special
importance
due
to
its
high
nitrogen-oxygen
content
and
possibility
serve
as
anion
counterpart
form
diverse
array
organic
inorganic
energetic
salts.
this
review,
we
summarized
main
achievements
on
synthesis
performance
hydroxytetrazole-based
materials.
Potential
applications
presented
compounds
their
environmental
compatibility
are
especially
emphasized.
Physical Chemistry Chemical Physics,
Год журнала:
2021,
Номер
23(29), С. 15522 - 15542
Опубликована: Янв. 1, 2021
The
solid-state
formation
enthalpies
of
63
CHNO
energetic
compounds
were
obtained
as
complementary
combinations
the
gas-phase
thermochemistry
from
predictive
quantum
chemical
calculations
and
phase
change
data
advanced
thermogravimetry.
