Facile fabrication of binary g-C3N4/NH2-MIL-125(Ti) MOF nanocomposite with Z-scheme heterojunction for efficient photocatalytic H2 production and CO2 reduction under visible light

Fuel, Год журнала: 2023, Номер 360, С. 130561 - 130561

Опубликована: Дек. 6, 2023

Язык: Английский

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Metal organic framework-based cathode materials for aqueous zinc-ion batteries: Recent advances and perspectives

Energy storage materials, Год журнала: 2024, Номер 65, С. 103168 - 103168

Опубликована: Янв. 6, 2024

Язык: Английский

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A Comprehensive Review on the Boosted Effects of Anion Vacancies in Photocatalytic Solar Water Splitting: Focus on g-C₃N₄ with Carbon and Nitrogen Vacancies

Energy & Fuels, Год журнала: 2024, Номер 38(10), С. 8406 - 8436

Опубликована: Май 1, 2024

As one of the best sustainable approaches for visible-light production hydrogen (H2) to meet energy demands, semiconductor-based photocatalysis has received broad interest in recent decades. The fundamental restrictions graphitic carbon nitride (g-C3N4) as a promising metal-free photocatalytic semiconductor water splitting, like insufficient harvesting and high electron–hole (e/h) pairs recombination, have limited its applications this goal. In regard, optical, charge separation, surface features g-C3N4 can be tuned via engineering C/N vacancies, which is reviewed here splitting by g-C3N4. Reports confirm that enhanced resulting from vacancies are helpful adsorption on surface, improving water-splitting kinetics. First Review, improvements structural optical characteristics introducing especially nitrogen will discussed illustrate better performance. Then, various strategies creating controlling reviewed. critical roles optimizing performance also described, finally advances defective oxidation addressed.

Язык: Английский

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Preferential heteroatom substitution into ZnIn2S4 nanosheets boosts photocatalytic hydrogen production

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 356, С. 124154 - 124154

Опубликована: Май 8, 2024

Язык: Английский

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Flatland of Graphene's derivatives: Classification, synthesis, mechanisms, role of defects, applications, and prospectives

Coordination Chemistry Reviews, Год журнала: 2025, Номер 528, С. 216421 - 216421

Опубликована: Янв. 8, 2025

Язык: Английский

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Leveraging the critical role of CoFe2O4/ZnWO4 heterostructure for the enhanced sonophotocatalytic degradation of tetracycline, chlortetracycline, and chloramphenicol: Mechanism insights and pathways

Journal of Cleaner Production, Год журнала: 2025, Номер unknown, С. 144846 - 144846

Опубликована: Янв. 1, 2025

Язык: Английский

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Leveraging the photocatalytic Cr (VI) reduction by an IRMOF-3@NH2-MIL-101 (Fe) heterostructure based on interfacial Lewis acid-base interaction

Chemosphere, Год журнала: 2024, Номер 352, С. 141473 - 141473

Опубликована: Фев. 19, 2024

Язык: Английский

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Advances in hybrid strategies for enhanced photocatalytic water splitting: Bridging conventional and emerging methods

Applied Physics Reviews, Год журнала: 2024, Номер 11(4)

Опубликована: Окт. 8, 2024

Significant efforts have been dedicated to hydrogen production through photocatalytic water splitting (PWS) over the past five decades. However, achieving commercially viable solar-to-hydrogen conversion efficiency in PWS systems remains elusive. These face intrinsic and extrinsic challenges, such as inadequate light absorption, insufficient charge separation, limited redox active sites, low surface area, scalability issues practical designs. To address these issues, conventional strategies including heterojunction engineering, plasmonics, hybridization, lattice defects, sensitization, upconversion processes extensively employed. More recently, innovative hybrid like photonic crystal-assisted polarization field-assisted emerged, which improve absorption separation by harnessing slow photon effect, multiple scattering, piezoelectric, pyroelectric, ferroelectric properties of materials. This review article aims provide a comprehensive examination summary new synergistic approaches, integrating plasmonic effects, processes, crystal photocatalysis. It also explores role temperature suppressing exciton recombination during photothermic highlights emerging effects magnetic fields, periodic illumination, many-body large-hole polaron, anapole excitations, hold significant potential advance technology facilitate renewable generation.

Язык: Английский

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Optimized separation of C2H2 from binary mixtures of C2H2/CO2 and C2H2/C2H4 by coordinative copper(I) metal nodes modified from HKUST-1

Chemical Engineering Journal, Год журнала: 2024, Номер 491, С. 152034 - 152034

Опубликована: Май 8, 2024

Acetylene (C2H2), an industrially important gas, is produced by steam cracking of hydrocarbons and inevitably contains traces ethylene (C2H4) carbon dioxide (CO2) as impurities. Metal-organic frameworks (MOFs) further post-modified MOFs are versatile promising adsorbents for energy-efficient C2H2/C2H4 C2H2/CO2 separation selective adsorption C2H2 compared to energy-consuming conventional methods. Herein, Cu(I) ion generated structures from post-synthetic modification HKUST-1 chosen sites over both C2H4 CO2 gases. Protective ions were post-coordinative reduction Cu(II) nodes a using hydroquinone reducing agent create robust adsorptive sites. In the metal node reduced (HKUST-1-HQ), selectivity was enhanced not only but also presence site, virtue copper(I)-alkynyl chemistry. breakthrough test, did occur at coordinatively unsaturated site (HKUST-1), whereas capability appeared after monovalent copper introduced. Enhanced observed HKUST-1-HQ. The behavior (triple bond), (double (opposite quadruple moment) copper(II) open copper(I) originating same structure respectively studied understand gas sorption. HKUST-1-HQ, study four types possible Cu (Nodes II, III, IV, V) adsorbates revealed that Node IV preferential other three sites, CUS (bare HKUST-1). DFT computational simulation successfully demonstrated type plausible C2H2. Overall, HKUST-1-HQ exhibits greater moisture stability, improved selectivity, repeatability adsorbent.

Язык: Английский

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From construction strategies to applications: Multifunctional defective metal-organic frameworks

Coordination Chemistry Reviews, Год журнала: 2024, Номер 526, С. 216356 - 216356

Опубликована: Дек. 9, 2024

Язык: Английский

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