Advanced Materials,
Год журнала:
2024,
Номер
36(35)
Опубликована: Июнь 21, 2024
Real-time
continuous
monitoring
of
non-cognitive
markers
is
crucial
for
the
early
detection
and
management
chronic
conditions.
Current
diagnostic
methods
are
often
invasive
not
suitable
at-home
monitoring.
An
elastic,
adhesive,
biodegradable
hydrogel-based
wearable
sensor
with
superior
accuracy
durability
real-time
human
health
developed.
Employing
a
supramolecular
engineering
strategy,
pseudo-slide-ring
hydrogel
synthesized
by
combining
polyacrylamide
(pAAm),
β-cyclodextrin
(β-CD),
poly
2-(acryloyloxy)ethyltrimethylammonium
chloride
(AETAc)
bio
ionic
liquid
(Bio-IL).
This
novel
approach
decouples
conflicting
mechano-chemical
effects
arising
from
different
molecular
building
blocks
provides
balance
mechanical
toughness
(1.1
×
10
Abstract
Conductive
hydrogels
can
be
prepared
by
incorporating
various
conductive
materials
into
polymeric
network
hydrogels.
In
recent
years,
have
been
developed
and
applied
in
the
field
of
strain
sensors
owing
to
their
unique
properties,
such
as
electrical
conductivity,
mechanical
self‐healing,
anti‐freezing
properties.
These
remarkable
properties
allow
hydrogel‐based
show
excellent
performance
for
identifying
external
stimuli
detecting
human
body
movement,
even
at
subzero
temperatures.
This
review
summarizes
application
fabrication
working
different
modes.
Finally,
a
brief
prospectus
development
future
is
provided.
Advanced Functional Materials,
Год журнала:
2021,
Номер
31(42)
Опубликована: Июль 20, 2021
Abstract
Inspired
by
the
human
skin,
electronic
skins
(e‐skins)
composed
of
various
flexible
sensors,
such
as
strain
sensor,
pressure
shear
force
temperature
and
humility
delicate
circuits,
are
emerged
to
mimic
sensing
functions
skins.
In
this
review,
strategies
realize
versatile
functionalities
natural
skin‐like
e‐skins,
including
strain‐,
pressure‐,
force‐,
temperature‐
humility‐sensing
abilities,
well
self‐healing
ability
other
summarized.
Some
representative
examples
high‐performance
e‐skins
their
applications
outlined
discussed.
Finally,
outlook
future
is
presented.
ACS Applied Materials & Interfaces,
Год журнала:
2022,
Номер
14(30), С. 34455 - 34469
Опубликована: Июль 20, 2022
Engineered
wound
dressing
materials
with
excellent
injectability,
self-healing
ability,
tissue-adhesiveness,
especially
the
ones
possessing
potential
therapeutic
effects
have
great
practical
significance
in
healthcare.
Herein,
an
injectable
quaternary
ammonium
chitosan
(QCS)/tannic
acid
(TA)
hydrogel
based
on
QCS
and
TA
was
designed
fabricated
by
facile
mixing
of
two
ingredients
under
physiological
conditions.
In
this
system,
hydrogels
were
mainly
cross-linked
dynamic
ionic
bonds
hydrogen
between
TA,
which
endows
injectable,
self-healing,
adhesive
properties.
Benefitting
from
inherent
antioxidative,
antibacterial,
hemostatic
abilities
QCS,
showed
superior
reactive
oxygen
species
scavenging
activity,
broad-spectrum
antibacterial
as
well
rapid
capability.
Moreover,
QCS/TA2.5
(containing
2.5%
TA)
exhibited
biocompatibility.
The
vivo
experiments
also
that
not
only
rapidly
stopped
bleeding
arterial
deep
incompressible
wounds
mouse
tail
amputation,
femoral
artery
hemorrhage,
liver
incision
models
but
significantly
accelerated
healing
a
full-thickness
skin
model.
For
potentials
listed
above,
multifunctional
offers
promising
network
material
for
both
hemostasis
repair.
Abstract
Rapid
advances
in
wearable
electronics
and
mechno‐sensational
human–machine
interfaces
impose
great
challenges
developing
flexible
deformable
tactile
sensors
with
high
efficiency,
ultra‐sensitivity,
environment‐tolerance,
self‐sustainability.
Herein,
a
hydrogel
sensor
(THS)
based
on
micro‐pyramid‐patterned
double‐network
(DN)
ionic
organohydrogels
to
detect
subtle
pressure
changes
by
measuring
the
variations
of
triboelectric
output
signal
without
an
external
power
supply
is
reported.
By
first
time
pyramidal‐patterned
fabrication
method
laminated
polydimethylsiloxane
(PDMS)
encapsulation
process,
self‐powered
THS
shows
advantages
remarkable
flexibility,
good
transparency
(≈85%),
excellent
sensing
performance,
including
extraordinary
sensitivity
(45.97
mV
Pa
−1
),
fast
response
(≈20
ms),
very
low
limit
detection
(50
Pa)
as
well
stability
(36
000
cycles).
Moreover,
LiBr
immersion
treatment
method,
possesses
long‐term
hyper
anti‐freezing
anti‐dehydrating
properties,
broad
environmental
tolerance
(−20
60
°C),
instantaneous
peak
density
20
µW
cm
−2
,
providing
reliable
contact
outputs
different
materials
detecting
slight
human
motions.
integrating
acquisition/process
circuit,
self‐power
ability
utilized
switching
button
control
electric
appliances
robotic
hands
simulating
finger
gestures,
offering
its
potentials
for
multi‐functional
electronic
applications.
Chemical Society Reviews,
Год журнала:
2023,
Номер
52(9), С. 2992 - 3034
Опубликована: Янв. 1, 2023
The
flourishing
development
of
flexible
healthcare
sensing
systems
is
inseparable
from
the
fundamental
materials
with
application-oriented
mechanical
and
electrical
properties.
Thanks
to
continuous
inspiration
our
Mother
Nature,
hydrogels
originating
natural
biomass
are
attracting
growing
attention
for
their
structural
functional
designs
owing
unique
chemical,
physical
biological
These
highly
efficient
architectural
enable
them
be
most
promising
candidates
electronic
devices.
This
comprehensive
review
focuses
on
recent
advances
in
naturally
sourced
constructing
multi-functional
sensors
applications
thereof.
We
first
briefly
introduce
representative
polymers,
including
polysaccharides,
proteins,
polypeptides,
summarize
physicochemical
design
principles
fabrication
strategies
hydrogel
based
these
polymers
outlined
after
material
properties
required
presented.
then
highlight
various
techniques
devices,
illustrate
examples
wearable
or
implantable
bioelectronics
pressure,
strain,
temperature,
biomarker
field
systems.
Finally,
concluding
remarks
challenges
prospects
hydrogel-based
provided.
hope
that
this
will
provide
valuable
information
next-generation
build
a
bridge
between
as
matter
an
applied
target
accelerate
new
near
future.
ACS Applied Materials & Interfaces,
Год журнала:
2021,
Номер
13(12), С. 14612 - 14622
Опубликована: Март 16, 2021
Hydrogel-based
flexible
strain
sensors
have
shown
great
potential
in
body
movement
tracking,
early
disease
diagnosis,
noninvasive
treatment,
electronic
skins,
and
soft
robotics.
The
good
self-healing,
biocompatible,
sensitive
stretchable
properties
are
the
focus
of
hydrogel-based
sensors.
Dual
network
(DN)
hydrogels
hopeful
to
fabricate
self-healing
with
above
properties.
Here,
multifunctional
DN
prepared
via
a
combination
host–guest
interaction
β-cyclodextrin
ferrocene
dynamic
borate
ester
bonds
poly(vinyl
alcohol)
borax.
Carbon
nanotubes
used
endow
conductivity.
obtained
composite
possess
biocompatibility,
stretchability
(436%),
fracture
strength
(41.0
KPa),
property
(healing
efficiency
95%),
high
tensile
sensitivity
(gauge
factor
5.9).
as
detect
different
human
motions.
After
cutting,
healed
also
can
monitor
motions
stability.
In
addition,
hydrogel
may
track
respiratory
pig
lung
vitro.
This
work
exhibits
new
ideas
approaches
develop
for
constructing
Advanced Materials,
Год журнала:
2022,
Номер
34(26)
Опубликована: Март 8, 2022
Advances
in
wearable
epidermal
sensors
have
revolutionized
the
way
that
physiological
signals
are
captured
and
measured
for
health
monitoring.
One
major
challenge
is
to
convert
easily
readable
a
convenient
way.
possibility
based
on
visible
readouts.
There
range
of
materials
whose
optical
properties
can
be
tuned
by
parameters
such
as
temperature,
pH,
light,
electric
fields.
Herein,
this
review
covers
highlights
set
with
tunable
their
integration
into
Specifically,
recent
progress,
fabrication,
applications
these
summarized
discussed.
Finally,
challenges
perspectives
next
generation
devices
proposed.
Abstract
The
human
skin,
an
important
sensory
organ,
responds
sensitively
to
external
stimuli
under
various
harsh
conditions.
However,
the
simultaneous
achievement
of
mechanical/thermal
sensitivity
and
extreme
environmental
tolerance
remains
enormous
challenge
for
skin‐like
hydrogel‐based
sensors.
In
this
study,
a
novel
skin‐inspired
hydrogel–elastomer
hybrid
with
sandwich
structure
strong
interfacial
bonding
mechanical–thermal
multimode
sensing
applications
is
developed.
An
inner‐layered
ionic
hydrogel
semi‐interpenetrating
network
prepared
using
sodium
carboxymethyl
cellulose
(CMC)
as
nanofiller,
lithium
chloride
(LiCl)
transport
conductor,
polyacrylamide
(PAM)
polymer
matrix.
outer‐layered
polydimethylsiloxane
(PDMS)
elastomers
fully
encapsulating
endow
hybrids
improved
mechanical
properties,
intrinsic
waterproofness,
long‐term
water
retention
(>98%).
silane
modification
hydrogels
imparts
enhanced
strength
integrity.
exhibit
high
transmittance
(~91.2%),
fatigue
resistance,
biocompatibility.
multifunctional
sensors
assembled
from
realize
real‐time
temperature
(temperature
coefficient
approximately
−1.1%
°C
−1
)
responsiveness,
wide‐range
strain
capability
(gauge
factor,
~3.8)
over
wide
range
(from
−20°C
60°C),
underwater
information
transmission.
Notably,
dual‐parameter
sensor
can
recognize
superimposed
signals
strain.
designed
prototype
arrays
detect
magnitude
spatial
distribution
forces
temperatures.
comprehensive
performance
via
facile
method
superior
that
most
similar
previously
reported.
Finally,
study
develops
new
material
platform
monitoring
health
in
environments.
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