Functionalized covalent triazine frameworks as promising platforms for environmental remediation: A review

Cleaner Chemical Engineering, Год журнала: 2022, Номер 2, С. 100012 - 100012

Опубликована: Март 29, 2022

Covalent triazine frameworks (CTFs), an emerging subclass of contemporary high-performance nanoporous materials, have demonstrated their plausible potential in diverse real-world applications, for instance, adsorption, separation, catalysis, energy storage, photonics, and electronics. Similar to other supermolecular structures such as metal-organic (MOF) covalent organic (COFs), CTFs feature pre-designability post-synthetic chemical tunability. Thus, they deliver distinct physicochemical, optical, electrical, structural characteristics. Such features also endow with unique properties, including optional building blocks synthetic methods, increased specific surface area, considerable pore volume, accessible micro-and/or mesopores structures, superior chemical/thermal stability, heteroatom effect. Meanwhile, further improve the performance practice thus expand possible several comprising various functionalities been successfully synthesized. can be modified via either bottom-up (i.e., pre-synthetic) or functionalization strategies used environmental remediation implementations. In present review, current developments environment-related applications functionalized CTFs, CO2 capture, removal heavy metal species from aqueous solutions, radioiodine uptake, photocatalytic degradation pollutants, are discussed detail. Functionalized shown unprecedented adsorption capacity selectivity towards pollutants. It has revealed that main interaction mechanisms between adsorbate CTFs' surfaces electrostatic, acid-base, charge transfer, ion exchange, chelation, coordination, hydrogen-bonding, hydrophobic effect, π−π stacking mechanisms. more research is required bridge gap lab-scale remediation.

Язык: Английский

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Smart -borneol-loaded hierarchical hollow polymer nanospheres with antipollution and antibacterial capabilities

Materials Today Chemistry, Год журнала: 2022, Номер 26, С. 101252 - 101252

Опубликована: Ноя. 16, 2022

Язык: Английский

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Synthesis of hydroxyl-functional magnetic hypercrosslinked polymer as high efficiency adsorbent for sensitively detecting neonicotinoid residues in water and lettuce samples

Microchemical Journal, Год журнала: 2023, Номер 187, С. 108412 - 108412

Опубликована: Янв. 10, 2023

Язык: Английский

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pH-Sensitive adsorption of gastrointestinal drugs (famotidine and pantoprazole) as pharmaceutical pollutants by using the Au-doped@ZIF-90-glycerol adsorbent: insights from computational modeling

Journal of Materials Chemistry A, Год журнала: 2023, Номер 11(47), С. 26127 - 26151

Опубликована: Янв. 1, 2023

Gastrointestinal drug pollutants pose environmental risks. Our study explores the adsorption of famotidine (FA) and pantoprazole (PA) using Au-ddoped@ZIF-90-gglycerol adsorbent (A@Z/G), emphasizing pH-sensitive effects on ecosystems.

Язык: Английский

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Fluorescent Benzoxazine–Perylene Linked Covalent Organic Polymer as a Sensing Probe for Lead Ions and 2,4,6-Trinitrophenol

ACS Applied Polymer Materials, Год журнала: 2024, Номер 6(15), С. 9170 - 9179

Опубликована: Июль 22, 2024

Язык: Английский

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