Hyper-Crosslinked Porous Organic Nanomaterials: Structure-Oriented Design and Catalytic Applications DOI Creative Commons

Yiqian Luo,

Yixuan Mei,

Yang Xu

и другие.

Nanomaterials, Год журнала: 2023, Номер 13(18), С. 2514 - 2514

Опубликована: Сен. 8, 2023

Hyper-crosslinked porous organic nanomaterials, especially the hyper-crosslinked polymers (HCPs), are a unique class of materials that combine benefits high surface area, structure, and good chemical thermal stability all rolled into one. A wide range synthetic methods offer an enormous variety HCPs with different pore structures morphologies, which has allowed to be developed for gas adsorption separations, encapsulation, heterogeneous catalysis. Here, we present systematic review recent approaches size modulation morphological tailoring their applications We mainly compare effects on catalytic applications, aiming pave way researchers develop optimal performance modern applications.

Язык: Английский

Development of sulfonic acid-functionalized covalent organic polymer towards efficient adsorption of cationic dyes DOI Creative Commons

Nazanin Taheri,

Mohammad Dinari

Applied Surface Science Advances, Год журнала: 2023, Номер 18, С. 100543 - 100543

Опубликована: Дек. 1, 2023

Organic dyes, often found in textile wastewater and soft drinks, are a threat to environmental human well-being. Considering that adsorbents could be used alleviate such threats, the present work is focused on design of covalent organic polymer (COP) for adsorption cationic dyes. For this, COP was synthesized via Friedel-Crafts reaction subsequently functionalized with chlorosulfonic acid groups form sulfonated COP, denoted TC-COP-SO3H. Next, material's capacity, kinetics, recyclability were assessed. The capacity TC-COP-SO3H Basic Blue 41 46 higher than it before modification sulfonic groups. improved efficiency high dyes attributed increased density sites, which stems from favourable electrostatic interactions achieved post-synthetic COP.

Язык: Английский

Процитировано

16

Porous Organic Polymers: Promising Testbed for Heterogeneous Reactive Oxygen Species Mediated Photocatalysis and Nonredox CO2 Fixation DOI
Arkaprabha Giri, Abhijit Patra

The Chemical Record, Год журнала: 2022, Номер 22(9)

Опубликована: Июнь 8, 2022

Abstract Catalysts play a pivotal role in achieving the global need for food and energy. In this context, porous organic polymers (POPs) with high surface area, robust architecture, tunable pore size, chemical functionalities have emerged as promising testbeds heterogeneous catalysis. Amorphous POPs having functionalized interconnected hierarchical structures activate diverse range of substrates through covalent/non‐covalent interactions or act host matrix to encapsulate catalytically active metal centers. On other hand, conjugated been explored photoinduced transformations. personal account, we delineated evolution various specific pores Subsequently, retrospect our journey over last ten years towards designing fabricating amorphous catalysis, specifically photocatalytic reactive oxygen species (ROS)‐mediated transformations nonredox fixation CO 2 . We also outlined some future avenues POP‐based hybrid materials catalytic applications.

Язык: Английский

Процитировано

23

Removal of large class of organic pollutants and gold using Phloroglucinol/Resorcinol coupled Triazine-based porous organic polymer DOI
Nisar Ahamed Babujohn,

P.A. Shifana,

Amoluck Eluri

и другие.

Separation and Purification Technology, Год журнала: 2023, Номер 316, С. 123770 - 123770

Опубликована: Апрель 7, 2023

Язык: Английский

Процитировано

13

Carbonate-based hyper-cross-linked polymers with pendant versatile electron-withdrawing functional groups for CO2adsorption and separation DOI
Shuang‐Shuang Hou, Jiarui Hu, Xueting Liang

и другие.

Journal of Materials Chemistry A, Год журнала: 2022, Номер 10(28), С. 15062 - 15073

Опубликована: Янв. 1, 2022

The simple and highly efficient preparation of porous hyper-cross-linked polymers (HCPs) with high surface area manifold functionalities for high-performance CO 2 uptake selective separation has drawn significant attention in the past decade.

Язык: Английский

Процитировано

19

Hyper-Crosslinked Porous Organic Nanomaterials: Structure-Oriented Design and Catalytic Applications DOI Creative Commons

Yiqian Luo,

Yixuan Mei,

Yang Xu

и другие.

Nanomaterials, Год журнала: 2023, Номер 13(18), С. 2514 - 2514

Опубликована: Сен. 8, 2023

Hyper-crosslinked porous organic nanomaterials, especially the hyper-crosslinked polymers (HCPs), are a unique class of materials that combine benefits high surface area, structure, and good chemical thermal stability all rolled into one. A wide range synthetic methods offer an enormous variety HCPs with different pore structures morphologies, which has allowed to be developed for gas adsorption separations, encapsulation, heterogeneous catalysis. Here, we present systematic review recent approaches size modulation morphological tailoring their applications We mainly compare effects on catalytic applications, aiming pave way researchers develop optimal performance modern applications.

Язык: Английский

Процитировано

11