Nanomaterials,
Год журнала:
2023,
Номер
13(18), С. 2514 - 2514
Опубликована: Сен. 8, 2023
Hyper-crosslinked
porous
organic
nanomaterials,
especially
the
hyper-crosslinked
polymers
(HCPs),
are
a
unique
class
of
materials
that
combine
benefits
high
surface
area,
structure,
and
good
chemical
thermal
stability
all
rolled
into
one.
A
wide
range
synthetic
methods
offer
an
enormous
variety
HCPs
with
different
pore
structures
morphologies,
which
has
allowed
to
be
developed
for
gas
adsorption
separations,
encapsulation,
heterogeneous
catalysis.
Here,
we
present
systematic
review
recent
approaches
size
modulation
morphological
tailoring
their
applications
We
mainly
compare
effects
on
catalytic
applications,
aiming
pave
way
researchers
develop
optimal
performance
modern
applications.
Applied Surface Science Advances,
Год журнала:
2023,
Номер
18, С. 100543 - 100543
Опубликована: Дек. 1, 2023
Organic
dyes,
often
found
in
textile
wastewater
and
soft
drinks,
are
a
threat
to
environmental
human
well-being.
Considering
that
adsorbents
could
be
used
alleviate
such
threats,
the
present
work
is
focused
on
design
of
covalent
organic
polymer
(COP)
for
adsorption
cationic
dyes.
For
this,
COP
was
synthesized
via
Friedel-Crafts
reaction
subsequently
functionalized
with
chlorosulfonic
acid
groups
form
sulfonated
COP,
denoted
TC-COP-SO3H.
Next,
material's
capacity,
kinetics,
recyclability
were
assessed.
The
capacity
TC-COP-SO3H
Basic
Blue
41
46
higher
than
it
before
modification
sulfonic
groups.
improved
efficiency
high
dyes
attributed
increased
density
sites,
which
stems
from
favourable
electrostatic
interactions
achieved
post-synthetic
COP.
The Chemical Record,
Год журнала:
2022,
Номер
22(9)
Опубликована: Июнь 8, 2022
Abstract
Catalysts
play
a
pivotal
role
in
achieving
the
global
need
for
food
and
energy.
In
this
context,
porous
organic
polymers
(POPs)
with
high
surface
area,
robust
architecture,
tunable
pore
size,
chemical
functionalities
have
emerged
as
promising
testbeds
heterogeneous
catalysis.
Amorphous
POPs
having
functionalized
interconnected
hierarchical
structures
activate
diverse
range
of
substrates
through
covalent/non‐covalent
interactions
or
act
host
matrix
to
encapsulate
catalytically
active
metal
centers.
On
other
hand,
conjugated
been
explored
photoinduced
transformations.
personal
account,
we
delineated
evolution
various
specific
pores
Subsequently,
retrospect
our
journey
over
last
ten
years
towards
designing
fabricating
amorphous
catalysis,
specifically
photocatalytic
reactive
oxygen
species
(ROS)‐mediated
transformations
nonredox
fixation
CO
2
.
We
also
outlined
some
future
avenues
POP‐based
hybrid
materials
catalytic
applications.
Journal of Materials Chemistry A,
Год журнала:
2022,
Номер
10(28), С. 15062 - 15073
Опубликована: Янв. 1, 2022
The
simple
and
highly
efficient
preparation
of
porous
hyper-cross-linked
polymers
(HCPs)
with
high
surface
area
manifold
functionalities
for
high-performance
CO
2
uptake
selective
separation
has
drawn
significant
attention
in
the
past
decade.
Nanomaterials,
Год журнала:
2023,
Номер
13(18), С. 2514 - 2514
Опубликована: Сен. 8, 2023
Hyper-crosslinked
porous
organic
nanomaterials,
especially
the
hyper-crosslinked
polymers
(HCPs),
are
a
unique
class
of
materials
that
combine
benefits
high
surface
area,
structure,
and
good
chemical
thermal
stability
all
rolled
into
one.
A
wide
range
synthetic
methods
offer
an
enormous
variety
HCPs
with
different
pore
structures
morphologies,
which
has
allowed
to
be
developed
for
gas
adsorption
separations,
encapsulation,
heterogeneous
catalysis.
Here,
we
present
systematic
review
recent
approaches
size
modulation
morphological
tailoring
their
applications
We
mainly
compare
effects
on
catalytic
applications,
aiming
pave
way
researchers
develop
optimal
performance
modern
applications.
