Опубликована: Янв. 1, 2024
Язык: Английский
Опубликована: Янв. 1, 2024
Язык: Английский
Inorganic Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Фев. 2, 2025
Metal halide double perovskites with splendid optical features have been considerably investigated for optoelectronic applications. Herein, a series of Mn2+-doped Cs2NaLuCl6 perovskite crystals were prepared. Via adopting the density functional theory calculation, effect Mn2+ doping on electronic structure compound was discussed. It found that crystal can emit intense blue light from host self-trapped exciton (STE) emission. Excited by 320 nm, STE and emissions simultaneously observed in resulting crystals. Owing to efficient energy transfer Mn2+, polychromatic luminescence final products. Moreover, taking advantage various responses emission intensities temperature, thermometric characteristics investigated, their maximum relative sensitivity is 0.99% K-1, which hardly impacted content. Furthermore, prepared exhibit good X-ray radioluminescence properties, low detection limitation 0.99 μGyair s-1. Additionally, utilizing designed crystal, flexible imaging high resolution 20 lp mm-1 be operated high-temperature environment realized. These results indicated are suitable thermometry imaging.
Язык: Английский
Процитировано
2Ceramics International, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
1The Journal of Chemical Physics, Год журнала: 2025, Номер 162(16)
Опубликована: Апрель 22, 2025
All-inorganic halide double perovskites have attracted extensive attention as new luminescent materials owing to their high luminous efficiency and wide emission spectrum. In this work, blue-red bicolor Cs2NaGdCl6 (CNGC) perovskite nanocrystals doped with Sb3+/Ho3+ were prepared using a hydrothermal method. The incorporation of Sb3+ significantly enhanced the intrinsic “self-trapped excitons (STEs)” wide-band bright blue centered at 470 nm. On basis, different concentrations Ho3+ introduced achieve color tunable from red region, extremely quantum efficiencies 96.53% 92.17%, respectively. By use diverse methods, including spectroscopic analysis fluorescence lifetime, mechanism efficient luminescence related dopant was comprehensively explored. Results show that not only can enhance STEs CNGC but also has an activation effect on rare earth ion Ho3+, because it plays role bridge for two energy transfer channels between centers, details investigated. Thermal stabilities studied over temperature range 303–473 K good performances demonstrated fact PL intensities CNGC:1%Sb3+ CNGC:1%Sb3+/10%Ho3+ 423 75.1% 70.1% compared those 303 K, With CNGC:1%Sb3+/10Ho3+ used, UV light-emitting diode activated devices fabricated characterized. emissions suggest materials’ prominent potential in application plant lighting. Finally, white-light sole matrix, strategy tri-doping Tb3+ proposed based principle three primary colors. device fabrication CNGC:1%Sb3+/10%Ho3+/2.5%Tb3+ sample characterization processes prove its feasibility then provide valuable insights design Sb ion-doped lead-free toward easily which be applied various fields.
Язык: Английский
Процитировано
1Journal of Materials Chemistry C, Год журнала: 2024, Номер 12(38), С. 15761 - 15767
Опубликована: Янв. 1, 2024
Sb 3+ /Ln co-doped Cs 2 NaGdCl 6 double perovskite was prepared. The energy transfer relationship between and Tb explored. White phosphors with CIE coordinates of (0.34, 0.33) were obtained by introducing Ho into the :Sb ,Tb .
Язык: Английский
Процитировано
4Advanced Functional Materials, Год журнала: 2024, Номер unknown
Опубликована: Авг. 25, 2024
Abstract This study presents the Br‐rich in situ synthesis of blue‐emitting 2D CsPbBr 3 nanoplatelets (NPLs) with various Br/Pb ratios using ZnBr 2 as a Br precursor to enhance ion adsorption significantly. leads effective passivation surface defects, particularly Pb−Br bonds, by increasing positive charge density around Pb atoms, thus creating stable bonding environment and reducing defect formation. Consequently, photoluminescence quantum yield (PLQY) improves from 31.15% for ratio 87.2% 6. NPLs 6 also exhibit longer lifetimes (16.69 ns) slower bleach recovery dynamics, indicating fewer non‐radiative recombination pathways exciton dynamics. Additionally, demonstrated better thermal stability, an activation energy 124.3 meV, stronger binding. These exhibited enhanced UV tolerance at 43.9% water resistance 23.8%, making them suitable displays lighting. Furthermore, Br‐passivated are used blue emitters prototype white LEDs, achieving wide color gamut, 126.6% National Television Standards Committee 94.5% Rec. 2020, demonstrating their potential high‐quality lighting advanced display technologies.
Язык: Английский
Процитировано
3Luminescence, Год журнала: 2025, Номер 40(1)
Опубликована: Янв. 1, 2025
ABSTRACT Spectroscopic properties of Tb‐doped and Tb‐Ag codoped lithium tetraborate (LTB) glasses with Li 2 B 4 O 7 (or O–2B 3 ) composition are investigated analysed using electron paramagnetic resonance (EPR), optical absorption, photoluminescence (PL) excitation (PLE) spectra, PL decay kinetics absolute quantum yield (QY) measurements. spectra the show numerous narrow emission bands corresponding to 5 D → F J (J = 6–0) 5–3) transitions Tb 3+ (4 f 8 ions. The most intense band ions at 541 nm ( transition) is characterised by a lifetime slightly exceeding 2.6 ms. Ag‐containing glass two broad weakly resolved in violet‐green spectral range attributed Ag + nonplasmonic nanoclusters. Decay these nonmonoexponential, an average microsecond range. A significant enhancement intensity QY was observed LTB comparison glass. energy transfer (EET) mechanisms from nanoclusters were explored.
Язык: Английский
Процитировано
0Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Фев. 16, 2025
Abstract Real‐time, high‐precision X‐ray imaging is of critical importance in a wide range applications, from medical diagnostics to security screening. While lanthanide luminescent materials are among the most commonly used scintillators, achieving combination large‐area scalability, rapid response, and optimal performance remains challenging. Herein, perovskite‐inspired cerium halide nanocrystal scintillator presented with remarkable photoluminescence quantum yield approaching unity fast radiative recombination rate ≈29 ns. By leveraging these promising characteristics, demonstrated spatial resolution 12.21 lp mm −1 an ultra‐low detection limit 11.2 nGy s , alongside applications dynamic imaging. Based on paternal nanocrystals, versatile spectral tunability through alloying cation doping further explored, offering platform for future chemical structural design toward advanced scintillations other down‐conversion applications.
Язык: Английский
Процитировано
0Advanced Optical Materials, Год журнала: 2025, Номер unknown
Опубликована: Фев. 18, 2025
Abstract Scintillation materials play a significant role in the exploration of extreme space environments and high‐energy physics. Nevertheless, due to prevalence thermal quenching, most traditional scintillators are not capable stable X‐ray imaging at high‐temperature working mode. In this work, Ce 3+ Tb ions successfully co‐doped into Cs 2 NaGdCl 6 double perovskites (DPs) via solvothermal method, exhibiting unusual thermally enhanced scintillation performance. Specifically, radioluminescence intensity :Tb /Ce increases with temperature achieve large ratio 3.67 from 80 500 K. Interestingly, introduction brings dramatic increase thermoluminescence intensity, demonstrating that an increased number deep trap results suppression quenching. At same time, extra occurrence traps can be traced localized octahedral distortions around dopant ions. Moreover, flexible DP‐based film is fabricated by direct coating showing imaging. Ultra‐stable performance over 5 h realized under high 380 K film. The provide regulation strategy for exploring novel high‐performance temperatures.
Язык: Английский
Процитировано
0Ceramics International, Год журнала: 2025, Номер unknown
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
0Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161093 - 161093
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
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